94th Canadian Chemistry Conference and Exhibition


Organic Chemistry

Monday AM

OR10513e

General Session

Organizer(s) - J.L. Gleason; H. Lebel
Chair(s) - M. Jha

08:00 01680 Controlled and Chemoselective Reductions of Secondary and Tertiary Amides : Versatile Applications of HEH and Et3SiH as Reducing Agents Pelletier G., Bechara W.S., Barbe G., *Charette A.B.
08:20 01681 Advances in the Photochemical Rearrangement of N-mesyloxylactams : Inter and Intra-molecular Trapping with C-nucleophiles Pichette S., Lessard J., *$Spino C.
08:40 01682 BINOL-Imidazolium Salts: From Thermal Properties To Catalytic Studies Vidal M., *Schmitzer A.R.
09:00 01683 Pd-Catalyzed Synthesis of Indoles via Cross-Coupling/Alkyne Cyclization Chemistry Involving Ammonia, Methylamine and Hydrazine Alsabeh P.G., Lundgren R.J., Longobardi L.E., *$Stradiotto M.
09:20 01684 Amination with Pd-NHC Complexes: Effects of the Oxidative Addition and Amine Partners Hoi K.H., Calimsiz S., Froses R.D.J., Hopkinson A.C., *$Organ M.G.
09:40 01685 Rhodium and Palladium Catalyzed Synthesis of 1,2-Dihydroquinolines: A Study of Multiple Ligand-Metal Interactions in Domino Catalysis Zhang L., *Panteleev J., $Lautens M.
10:00 Coffee Break
10:20 01686 Reactivity of Rhodaoxetanes and Related Structures: On the Road to Novel Catalytic Transformations Dauth A., *$Love J.A.
10:40 01687 Synthesis of Biologically Important Furanoterpenes: Furospongolide and Relatives Albert V., *$Boukouvalas J.
11:00 01688 Highly Enantioselective Intermolecular Stetter Reactions Employing a-Ketoesters as Versatile Acceptors Sánchez-Larios E., Thai K., Bilodeau F., *$Gravel M.
11:20 01689 Additive Effects in Silicon-Directed Nazarov Cyclization Joy S., Nakanishi W., *$West F.G.
11:40 01690 Stereoselective Synthesis of Both Stereoisomers of b-Fluorostyrenes Derivatives from a Common Intermediate Landelle G., Turcotte-Savard M.-O., Angers L., *Paquin J.-F.
12:00 01691 Rhodium(I)-Catalyzed Additions of Arylboronic Acids to Unactivated Alkenes and Nitriles: Studies of Regioselectivity and Novel Product Formation $Tsui G.C., Menard F., Glenadel Q., Lau C., *Lautens M.
12:20 End of Session

OR1516c

Green Chemistry and Catalysis in Honour of Tak-Hang (Bill) Chan

Organizer(s) - C.J. Li; A.B. Charette
Chair(s) - A. Schmitzer; C. Legault

08:00 01692 Some Organic Reactions in Pyrrolidinium Ionic Liquids *$Wong K.-Y., Wong W.-L., Ho K.-P.
08:40 01693 Transition Metal Nanoparticle Catalysts Stabilized by Functionalized Ionic Liquids Luska K.L., Stratton S.A., *$Moores A.
09:00 01694 Synthesis and Stability of Nanoparticle Catalysts in Ionic Liquid Media *$Scott R.W.J., Dash P., Banerjee A.
09:20 01695 Ionic Liquids: Alternative Solvents for Catalysis and Separations *$Singer R.D., Sonar S., Sadaphal S.A., Gomez A.T., Cuthbert T., Durand A., Ambrose K., Abraham T., Scammells P.J., Ford L., Atefi F., Harjani J.
10:00 Coffee Break
10:20 01696 CO2-Triggered Switchable Surfactants for the Oil Industry *$Jessop P.G., Horton J.H., Hodson P.V., Brown R.S.
11:00 01697 Low-Cost CO2 Capture Using Enzyme Catalysis *Savile C.K., Nguyen L., Alviso O., Balatskaya S., Benoit M., Fusman I., Geilhufe J., Gitin S., Liang J., Novick S., Parsons J., Zimmerman S., Lalonde J., Fradette S., Abokitse K., Belanger A.-S., Ceperkovic O., Daigle R., Gingras J., Madore E., Simard M.
11:40 01698 Asymmetric Organocatalysis Induced by the Anion of an Ionic Liquid Gauchot V., *Schmitzer A.
12:00 01699 Synthesis of Indoles by Conjugate Addition and Ligand-Free Copper-Catalyzed Intramolecular Arylation of Activated Acetylenes with o-Haloanilines $Gao D., *Back T.G.
12:20 End of Session

OR2516ab

Keith Fagnou Memorial Symposium

Organizer(s) - L. Barriault; A. Beauchemin
Chair(s) - Louis Barriault

08:40 01700 From Concerted Amination Reactivity to New Tethering Organocatalysts $Beauchemin A.M.
09:20 01701 Computationally-Guided Stereocontrol of the Combined C-H Activation/Cope Rearrangement *$Davies H.M.L., Lian Y.
10:00 Coffee Break
10:20 01702 Synthesis of Natural Products and Natural Product Hybrids *$Gleason J.L.
11:00 01703 Synthesis and Stereoselective Cross-Coupling of Chiral Alkylboronates Lee J.C.H., *$Hall D.G.
11:40 01704 Catalytic Transformations of Arenes *$Hartwig J.F.
12:20 End of Session

OR11510a

Nucleic Acids Chemistry and Biology (joint with BM8)

Organizer(s) - M.J. Damha; C.J. Wilds
Chair(s) - Masad Damha

08:00 See BM8.

12:00 End of Session

OR6511a

Peptide Science (joint with BM2)

Organizer(s) - W. Lubell; F. Polyak
Chair(s) - William Lubell

08:00 See BM2.

12:20 End of Session


Monday PM

OR1516c

Green Chemistry and Catalysis in Honour of Tak-Hang (Bill) Chan

Organizer(s) - C.J. Li; A.B. Charette
Chair(s) - A. Moores; T. Ollevier

13:40 01705 Expanding the Synthetic Utility of an Isopeptide Bond-forming Biocatalyst Gundersen M., Gnaccarini C., Ben Tahar W., Chica R.A., Gillet S.M.F., Lubell W.D., Keillor J.W., *$Pelletier J.N.
14:20 01706 R+N+A + i = RNAi? There is More to it Than That. New Advances in the Development of Oligonucleotide Based Therapeutics *$Damha M.J.
15:00 01707 Harnessing the Power of P450 Catalyzed Hydroxylations at Inactivated C-H Bonds Larsen A.T., $Auclair K., May E.
15:20 01708 Carboiodination of Alkenes Newman S.G., $Lautens M.
15:40 Coffee Break
16:00 01709 N-Heterocyclic Carbene-Catalyzed Ring Expansion of Azacycloalkane-2-carboxaldehydes for the Synthesis of Lactams Thai K., Wang L., Dudding T., Bilodeau F., *$Gravel M.
16:20 01710 Thiourea-Catalyzed Enantioselective Nucleophilic Addition to Thionium Ions *Stuart D.R., $Jacobsen E.N.
16:40 01711 Applications of New Boron Lewis Acid Catalysts to C-C and C-O Bond Formation *$McCubbin J.A., Voth S., Hiebert R., Nassar C., Hosseini H.
17:00 01712 Cu-Catalyzed Coupling of 2-Iodo Aryl Benzamides and Sulfonamides with 2-Bromophenols Kitching M.O., Hurst T.E., Korolev D., *$Snieckus V.A.
17:20 01713 Transition-Metal-catalyzed Amidation, Arylation and Acylation of Aryl C-H Bonds Through a Cross-dehydrogenative Coupling (CDC) Process Shuai Q., Li C.-J., *Deng G.
17:40 01714 Iron-catalyzed Cross-coupling and Epoxidation of Olefins *$Kozak C.M.
18:00 End of Session

OR2516ab

Keith Fagnou Memorial Symposium

Organizer(s) - L. Barriault; A. Beauchemin
Chair(s) - Andre Beauchemin

13:40 01715 Potent Inhibitors of Ice Recrystallization - Applications and New Directions *$Ben R.N., Capicciotti C.J., Leclere M., Davis K.
14:20 01716 Carbocycles from Cyclopropanes: New Directions in Cyclopropane Chemistry Kerr M.A.
15:00 01717 New Catalytic Reactions for Synthesis and Functionalization of Complex Molecules Montgomery J.
15:40 Coffee Break
16:00 01718 Direct C-H Functionalization of Organic Compounds: From Palladium-, to Copper-, to Iron-, to Metal-free Coupling Reactions *$Charette A.B.
16:40 01719 Harvest in the Domino and Gold-catalyzed Transformation Gardens: Chemical Stories from the Third Floor of D'Iorio Hall at UOttawa and Beyond *$Barriault L.
17:20 End of Session

OR11510a

Nucleic Acids Chemistry and Biology (joint with BM8)

Organizer(s) - M.J. Damha; C.J. Wilds
Chair(s) - Chris Wilds

13:40 See BM8.

17:40 End of Session

OR6511a

Peptide Science (joint with BM2)

Organizer(s) - W. Lubell; F. Polyak
Chair(s) - David Sabatino

14:00 See BM2.

18:00 End of Session

OR8511e

Modern Physical Organic Chemistry (joint with PT12)

Organizer(s) - D. Pratt
Chair(s) - Keith Ingold

13:40 01720 Investigation of Palladacycle-Catalyzed Methanolysis for Cleavage of Phosphorothioates and Thioamides Liu C.T., Neverov A.A., Maxwell C.I., Edwards D.R., Mosey N.J., *$Brown R.S.
14:20 01721 Mechanistic Studies on Glycosylation: Natural Abundance Kinetic Isotope Effects and Quantum Chemical Calculations Garrett G.E., *$Pratt D.A., Crich*$ D., Bohé L., Huang M.
14:40 01722 Kinetics of Alkyne-Nitrone Cycloadditions with Cyclic Nitrones for Bioconjugation Blake J.A., McKay C.S., Chigrinova M., Pezacki J.P.
15:00 01723 Challenges and Catalysis in Decarboxylations and Related Proton Transters *$Kluger R., Vandersteen A., Mundle S., Howe G.
15:40 Coffee Break
16:00 01724 Using Organic Chemistry to Make Nanoparticles and Nanoparticles to Direct Organic Chemistry Scaiano J.C.
16:40 01725 The Effects of Steric Interactions on the Chalcogen Abstraction Reactions by Transient Silylenes. Advances Towards Experimental Proof of Biradical Mechanism for Oxygen Abstraction Reactions Kostina S.S., *Leigh W.J.
17:00 01726 The Dependence of Reactivity Ratios for Radical Copolymerization on Structure *$Charton M.
17:20 01727 Acid-Base Catalysis in the Reactivity of Antioxidants with Peroxyl Radicals: a Kinetic and Mechanistic Discussion *$Valgimigli L.
18:00 End of Session

OR4516ab

Natural Product Chemistry (joint with BM13)

Organizer(s) - C. Spino

Bernard Belleau Award Lecture

17:20 01728 From Fundamental Studies in Organic Synthesis to Drug Discoveries Deslongchamps P.
18:00 End of Session


Tuesday AM

OR1516c

Green Chemistry and Catalysis in Honour of Tak-Hang (Bill) Chan

Organizer(s) - C.J. Li; A.B. Charette
Chair(s) - C.J. Li

08:00 01729 Optimization and Mechanistic Investigation of a Direct and Waste-Free Amidation of Carboxylic Acids Catalyzed by Boronic Acids at Room Temperature Gernigon N., Al-Zoubi R., *$Hall D.G.
08:20 01730 Metal Catalyst-Free Silicone Elastomers *Brook M.A., Gonzaga F., Grande J.B., Pascoal M., Fawcett A., Rambarran T.
08:40 01731 On Inventing New Reactions for Atom Economy *Trost B.M.
09:20 01732 "Green Macrocyclization": Developing Macrocyclization Methods at High Concentrations $Collins S.K.
10:00 Coffee Break
10:20 01733 Organoboron Catalysts for the Streamlined Synthesis of Carbohydrate Derivatives *$Taylor M.S., Chan L., Gouliaras C., Lee D.
11:00 01734 Desulfinylative and Decarboxylative Palladium-catalyzed Cross-Coupling Reactions as a Versatile Synthetic Tool *Forgione P.
11:20 End of Session

OR11510a

Nucleic Acids Chemistry and Biology (joint with BM8)

Organizer(s) - M.J. Damha; C.J. Wilds
Chair(s) - Chris Wilds; Masad Damha

08:20 See BM8.

11:20 End of Session

OR6511a

Peptide Science (joint with BM2)

Organizer(s) - W. Lubell; F. Polyak
Chair(s) - Felix Polyak

08:00 See BM2.

11:20 End of Session

OR8511e

Modern Physical Organic Chemistry (joint with PT12)

Organizer(s) - D. Pratt
Chair(s) - Derek Pratt

08:00 01735 Perturbation of Verdazyl Radical Electron Transfer Chemistry by Protons and by Metal Ions *$Hicks R.G., Anderson K.J., Nowak B.N., Johnston C.W.J.
08:40 01736 Applications of Plasmonics Toward the Development of Au Nanoparticles as Photocatalysts Hallett-Tapley G.L., Silvero J., González-Béjar M., Netto-Ferreira J., *Scaiano J.C.
09:00 01737 De Novo Electronic Push-Pull Bithiophene Derivatives: Fluorescence and Solvatochromism Study Bolduc A., Dong Y., McGregor N., *$Skene W.G.
09:20 01738 A Glimpse of the Chemistry of GeH2 in Solution. Direct Detection and Characterization of an Intramolecular Germylene-Alkene p-Complex Beleznay K.M., Billone P.S., Harrington C.R., Huck L.A., *$Leigh W.J.
10:00 Coffee Break
10:20 01739 Synthesis, Structure and Properties of New Pyrenophanes *$Bodwell G.J., MacKinnon M., Mannion M.R., Pleik S., Yang Y.
11:00 01740 The Investigation of Aromaticity of Cyclooctatetraenide Dianion with Fused Dimethyldihydropyrene Probe *Zhang P.R., Mitchell R.H., $Berg D.J.
11:20 End of Session

OR4513d

Natural Product Chemistry (joint with BM13)

Organizer(s) - C. Spino
Chair(s) - Bruno Ndzi

08:00 01741 Nature's Dirty Secrets. Genome Mining of the Microbial Terpenome Cane D.E., Zhu D., Seo M.-j.
08:40 01742 An Allylboration/Cycloisomerization/Diels-Alder Cycloaddition Sequence for the Construction of the Core Ring System of Pradimicin A Zilke L.C., *$Hall D.G.
09:00 01743 Studies Toward the Total Syntheses of Cephalosporolides E and F Chang S., *Britton R.
09:20 01744 Synthesis and Anticancer Activities of C-1 Analogs of Pancratistatin Vshyvenko S., Collins J., Scattolon J., *$Hudlicky T.
09:40 01745 Enantioselective Total Synthesis of Auxofuran Loach R.P., *$Boukouvalas J.
10:00 Coffee Break
10:20 01746 The Sequencing of the Polyketide Synthase Involved in Usnic Acid Biosynthesis *$Sorensen J.L., Abdel-Hameed M., Piercey-Normore M.P.
10:40 01747 Towards the Synthesis of Macropodumine I *$Belanger G., Boudreault J., Levesque F.
11:20 End of Session

OR7511b

Carbohydrates and Glycobiology (joint with BM6)

Organizer(s) - S. Sato; T. Lowary; D. Jakeman
Chair(s) - Sachiko Sato

08:00 See BM6.

11:20 End of Session


Tuesday PM

OR10516a

General Session

Organizer(s) - J.L. Gleason; H. Lebel

13:40 01748 The Piers-Rubinsztajn Reaction: A New Strategy for the Synthesis of Functional Silicones Grande J.B., $Brook M.A.
14:00 01749 Vapour-Liquid Equilibrium for Sevoflurane-Isoflurane Williston M., $Thurgood C.
14:20 01750 Synthesis of Some Nitrogen Containing Heterocyclic Compounds Using a Catalytic Amount of Zr-MCM-41 Nanoreactors Derikvand F., *Derikvand Z.
14:40 01751 Following Seterterpenoids Down the Food Chain Daoust J., $Ansersen R.J.
15:00 01752 New Mechanism for Heterologous Expression of Natural Product Biosynthetic Pathways *$Boddy C., Stevens D.C., Conway K., Pearce N.D.
15:20 01753 Asymmetric 1,3-Dipolar Cycloaddition Reactions of Azomethine Imines Generated In Situ from Verdazyl Radicals Youn B., $Georges M.K.
15:40 Coffee Break
16:00 01754 Zeolite Catalysis in Multicomponent Reaction (MCRs): Step Towards Green Chemistry *$Maheria K.C., Mistry S.R.
16:20 01755 The Effects of Sterics and Electronics on the Rate of Arene Hydrogenation with various Bipyridine Stabilized Rhodium Nanoparticle Catalysts Dykeman R.R., Yan N., Yuan Y., Scopelliti R., Dyson P.J.
16:40 01756 Synthesis and Application of Nitrogen-Containing Polymers as Additives for Aqueous Solutions with Switchable Ionic Strength Robert T., Mercer S.M., *Jessop P.G.
17:00 01757 Direct Detection of Transient Diphenylstannylene and Studies of its Reactivity in Solution by Laser Flash Photolysis Methods Duffy I.R., *$Leigh W.J.
17:20 01758 Theoretical Study of the Effect of Heavy Water on Acid-Base Equilibria *$Mora-Diez N., Formoso E., Fransbergen T.S., Tremaine P.R.
17:40 01759 Probing the Role of the Sidechain on the Potent Antioxidant Activity of N-Tocopherol, a Pyridinol Analogue of Vitamin E Harjani J.R., *$Pratt D.A.
18:00 01760 Transition Metal Complexes Featuring a Novel Carbene-Based PCP Ligand Borau-Garcia J., Bosch M.J., *$Roesler R.
18:20 End of Session

OR1516c

Green Chemistry and Catalysis in Honour of Tak-Hang (Bill) Chan

Organizer(s) - C.J. Li; A.B. Charette
Chair(s) - A. Charette; P. McBreen

13:40 01761 Recent Advances in Click Chemistry Sharpless K.B.
14:20 01762 Development of Novel Green Lewis Acid Catalysts for Asymmetric Bond-forming Reactions *$Ollevier T.
15:00 01763 A Multicomponent Approach to Splitomicin Analogs *$Jha A., Vaughan D.
15:20 01764 Design and Mechanistic Study of Chiral Rh(II)-Carboxylate Catalysts for Enantioselective Cyclopropanation Reactions with Diacceptor Diazo Compounds Lindsay V.N.G., *Charette A.B.
15:40 Coffee Break
16:00 01765 Is Electrocatalytic Hydrogenation a Synthetically Useful and Green Electrochemical Process? *$Lessard J.
16:40 01766 Advances in Hydroamination Catalysis for the Efficient Assembly of N-Heterocycles and Amine Containing Small Molecules Schafer L.L.
17:20 01767 A Tethered Bis(ureate) Zirconium Catalyst for Hydroalkynylation: Synthesis of Z-Enynes Platel R.H., $Schafer L.L.
17:40 01768 Towards a Visible Light Mediated Synthesis of Helicenes Hernandez-Perez A.C., $Collins S.K., Zysman-Colman E., Ladouceur S.
18:00 End of Session

OR11510a

Nucleic Acids Chemistry and Biology (joint with BM8)

Organizer(s) - M.J. Damha; C.J. Wilds
Chair(s) - Yingfu Li; Dipankar Sen

13:40 See BM8.

17:40 End of Session

OR8511e

Modern Physical Organic Chemistry (joint with PT12)

Organizer(s) - D. Pratt
Chair(s) - Jeffrey Keillor

13:40 01769 Structural and Solvent Effects on the Hydrogen Abstraction Reactions from Carbon by Alkoxyl Radicals. The Role of Hydrogen Bonding *Bietti M., DiLabio G.A., Salamone M.
14:20 01770 Hydrolytic Decarboxylation of Indole-3-Carboxylic Acid Vandersteen A.A., Mundle S.O.C., Lacrampe-Couloume G., Sherwood Lollar B., *$Kluger R.
14:40 01771 Nucleophilic Additions to Carbonyl Groups via Specific Acid Catalysis Mechanism. Rule or Exception? Reyes L., Nicolás I., *Mora-Diez N., $Alvarez-Idaboy J.R.
15:00 01772 Radical Clocks as Probes of Reaction Mechanisms on Silicon Surfaces *DiLabio G.A.
15:40 Coffee Break
16:00 01773 Fundamental Studies and New Applications of Halogen Bonding in Solution *$Taylor M.S., Chudzinski M.G., Dimitrijevic E., McClary C.A., Sarwar M.G.
16:40 01774 Templating Solution Behavior of Small Polyamines for Use as Switchable Water Additives Mercer S.M., Dixon D.V., Robert T., $Jessop P.G.
17:00 01775 C-H...O Participation in the Dimers of Aromatic N-Sulfinylhydrazines Boateng S., *$Muchall H.M.
17:20 01776 Superior Anion Binding by Tetrazole- and Guanidinium-based Hosts: Learning About Structure and Solvation Effects from Drugs and Proteins *$Hof F., Pinter T., Courtemanche R.J.M., Wang X.
18:00 End of Session

OR4513d

Natural Product Chemistry (joint with BM13)

Organizer(s) - C. Spino
Chair(s) - Guillaume Belanger

13:40 01777 Interrupted Nazarov Reactions Using Vinyl Siloxyallenes. Wu Y.K., *West F.G.
14:00 01778 Towards the Total Synthesis of (±)-Vinigrol $Poulin J., Grise-Bard C.M., *Barriault L.
14:20 01779 Development of the Interrupted Nazarov Cyclization of Allenyl Vinyl Ketones, with Application to the Total Synthesis of (-)-Roseadione Marx V.M., $Burnell D.J.
14:40 01780 New Chemical Keys to Unlock the Production of Microbial Antibiotics Corre C.
15:20 01781 Studies Towards a Total Synthesis of (-)-Lepadiformine A Wickenden J.G., *$Sammis G.M.
15:40 Coffee Break
16:00 01782 Development of Ring-forming Processes for the Synthesis of Natural Products *$Burnell D.J., Stamp C.T.M., Gao F., Thornton P.D., Marx V.M.
16:40 01783 An Inverse Electron Demand Diels-Alder (IEDDA) Approach to the Total Synthesis of Defucogilvocarcins Nandaluru P.R., *Bodwell G.J.
17:00 01784 Synthesis of Aspergillide B via a Novel Tetrahydrofuran Ring Expansion Stevens A.C., *$Pagenkopf B.L.
17:20 01785 Natural Products From Octocorals Kerr R.
18:00 End of Session

OR7511b

Carbohydrates and Glycobiology (joint with BM6)

Organizer(s) - S. Sato; T. Lowary; D. Jakeman
Chair(s) - Todd Lowary

13:40 See BM6.

18:00 End of Session

OR12512c

New Trends in Practical Synthesis and Scale Up (joint with IC7)

Organizer(s) - N. Chopra; D. Desilets
Chair(s) - Naveen Chopra; Denis Desislets

13:40 See IC7.

18:00 End of Session

ORpos517abc

Poster Session

From 17:40 until 20:30

17:40 01786 From Amino Acids and Benzene Derivatives via Friedel-Crafts Acylation to Amino Ketones, Amino Alcohols and Amines Teufel B.C., Nagel U.
17:40 01787 Factors That Influence Low Vitamin B12 Level Among College Students *$Obeidat B., Habib-Allah B., Al-Azzam S.
17:40 01788 The Microwave-Assisted Synthesis of N-Protected-L-Homoserinec-Lactones from L-Aspartic Acid *Singh S.P., Michaelides A., $Schwan A.L.
17:40 01789 Appended Prodigisenes for Improved Targetting of Breast Cancer Cells Marchal E., Uddin Md.I., Hawco C., Diaz R.I. S., Thompson A.
17:40 01790 The Synthesis, Resolution, and Determination of Absolute Stereochemistry of 1'-Substituted Spiro[imidazolidine-4,3'-indole]-2,2',5(1'H)-triones *Woo S., Buon C., Holmen A.G., Leung C., $Tomaszewski M.J., Walpole C.
17:40 01791 Isolation and Structure Determination of an Unusual Fused Bis(pyrrole) Skeleton Smithen D.A., Cameron T.S., Thompson A.
17:40 01792 Synthesis of Pyrrolo[3,2-e][1,4]diazepin-2-ones on Solid Support Dufour-Gallant J., Boutard N., *Lubell W. D.
17:40 01793 Supercritical Fluid Extraction and Hydroprocessing of New Brunswick Shale Oils $Riley S., *McGrady G.S., Romero-Zeron L.
17:40 01794 An Approach to Cyclic Compounds via Nazarov Reaction and Intramolecular [4 + 3] Cyclization Morgan T.D.R., $Burnell D.J.
17:40 01795 Preparation of 3-Cyano-3-arylpropanols from Aryl Ethers by the Smiles Rearrangement Grewal R., Kosowan J., *$Wood T.E.
17:40 01796 Synthetic Studies Toward Some New Macrocyclic Compounds and Their Complexation Behaviour Sleem H., Dawe L.N., *Georghiou P.E.
17:40 01797 An Investigation of the Reactivity of Boron Nitronates With Aldehydes *$Pottie I.R., MacDonald F.K., Carneiro K.M.M, Jaeschke A.J.
17:40 01798 Novel Synthesis of Polysubstituted Pyridine Derivatives from b-Sulfonylvinylamines Lau C., Tsui G.C., Lautens M.
17:40 01799 Synthesis of 1-Substituted Oxabenzonorbornadienes Haner J., Jack K., Nagireddy J., Raheem M.A., *$Tam W.
17:40 01800 Mild Selective Reduction of Tertiary Amides to Aldehydes via the In Situ Generated Schwartz Reagent [Cp2Zr(H)Cl]. Link to the Directed ortho Metalation (DoM) Reaction $Zhao Y., Morin J., *Snieckus V.
17:40 01801 Synthesis and Properties of Molecular Probes for Cystic Fibrosis Research Alkhouri B., *$Viirre R.D.
17:40 01802 Palladium(II)-Catalyzed Preparation of Aryl Ketones from Aryl Sulfinates Behrends M., Sävmarker J., Sköld C., *Larhed M.

OR General - Graduate Student Poster Competition

17:40 01803 Stereocontrolled Access to Unsymmetrical 1,1-Diaryl-2-fluoroethenes Landelle G., Turcotte-Savard M.-O., Marterer J., Champagne P. A., *Paquin J.-F.
17:40 01804 Reactions of Donor-Acceptor Cyclobutanes with Terminal Alkynes: Single Step Access to Dihydrooxepines Machin B.P., $Pagenkopf B.L.
17:40 01805 Synthesis and Characterization of a New Class of p-Extended BODIPY Dyes Guecha D., $Pollard M.M., *Orellana A.
17:40 01806 SN2 Reaction of Activated Alkyl Fluorides Champagne P.A., Pomarole J., *Paquin J.-F.
17:40 01807 The Vinylogous Aza-Morita-Baylis-Hillman Reaction of Activated 1,3-Butadienes Clary K.N., $Back T.G.
17:40 01808 Ruthenium Catalyzed Ring Opening Reactions of Substituted Oxabenzanorbornadienes Jack K., $Tam W.
17:40 01809 Novel and Efficient One-step Conversion of Benzonitrile into Methylarene Under Mild Conditions Ouellet E., Poirier D.
17:40 01810 Synthesis of 1,3,4-Oxadiazoles and Other N-Containing Heterocyclic Compounds using [Et2NSF2]BF4 as Cyclodehydration Agent $Pouliot M.-F., Angers L., *Paquin J.-F.
17:40 01811 Development of Synthetic Protocols for the Synthesis of Heterocyclic Compound Libraries Todorovic N., *Capretta A.
17:40 01812 Organocatalytic Tether Formation: A Strategy Enabling Directed Intermolecular Amination Reactions MacDonald M.J., Ng P.J., Schipper D., $Beauchemin A.M.
17:40 01813 Synthesis of Heterocycle-substituted Cyclopentanones by Interception of the Nazarov Reaction LeFort F.M., Marx V.M., $Burnell D.J.
17:40 01814 One-pot Formation of 1-Iodoalkynes from Primary Haloalkanes and Iodoform Pelletier G., Lie S., Mousseau J.J., *Charette A.B.
17:40 01815 The Stereoselective Synthesis of Vinylic b-amino Sulfoxides and their Subsequent Cyclization Soderman S.C., $Schwan A.L.
17:40 01816 Directed ortho Metalation Chemistry. Towards the Development of a Boron Based Directing Metal Group Cosman J.L., Board J., Wagner H., $Snieckus V.
17:40 01817 Optimization of a Palladium-catalyzed Desulfinylative Cross-coupling Reaction of Heteroaromatic Sulfinates and Aryl Halides Sévigny S., *$Forgione P.
17:40 01818 Carbon Disulfide and its Reactivity with Nitrogen Containing Compounds Ang M.T.C., *$Jessop P.G.
17:40 01819 Advances and Applications in Aqueous Olefination Reactions Employing Trialkylphosporanylides $McLeod D., *McNulty J.
17:40 01820 E/Z Selectivity in the Ruthenium-mediated Metathesis of Allyl Alcohol Derivatives Moulins J.R., $Burnell D.J.
17:40 01821 Synthesis of Chromopyrrolic Acid Analogues by a Suzuki Cross-Coupling Strategy Groom K.A., Snieckus V.
17:40 01822 The Tandem Cyclopropane Ring-Opening/Conia-ene Reaction Grover H., *Lebold T., Leduc A., $Kerr M.
17:40 01823 Synthesis of Dihydro-1,2-Oxazines via Palladium Catalyzed Oxidative Decarboxylation Humenny W.J., *Kyriacou P., Sapeta K., Karadeolian A., $Kerr M.A.
17:40 01824 Recent Developments in Asymmetric Buchwald-Hartwig Reactions Matarazzo A., *$Viirre R.D.
17:40 01825 Progress Toward the Synthesis of Labeled Derivatives of the Cystic Fibrosis Drug, VX-770 Elmallah S.A., *$Viirre R.D.
17:40 01826 Towards a Metal-catalyzed Annulation Route to Pyridines Whitmore K.M., *Beauchemin A.M.
17:40 01827 A Novel Synthesis of Benzothiopyran S,S-Dioxides *Hossain M.S., $Schwan A.
17:40 01828 Electrocyclizations and Domino Reactions Leading to Highly Substituted Indenes and 1,2,3,4-Thiatriazoles Rosocha G.Y., *Batey R.A.
17:40 01829 Palladium Catalyzed Synthesis of Acyl Pyrroles from Aryl Halides Chtchemelinine A., Rosa D., Bondarenko G., *$Orellana A.
17:40 01830 Taking a Stroll Around Azaindoles: The peri-Metalation Approach towards Polysubstituted 7-Azaindoles Schneider C., Toutov A., David E., *$Snieckus V.
17:40 01831 Amide-based Macrocycles Derived from 4,4'-methylenebis(3-methoxy-2-naphthoylchloride) and their Derivatives AlHujran T.A., Dawe L.N., $Georghiou P.E.

Organometallic Reagents for Organic Synthesis posters

17:40 01832 Metal-Catalyzed Intramolecular [4+2] Cycloadditions of Alkynyl Halides Tigchelaar A., Tam W.
17:40 01833 Synthesis of Pyridylidene Pincer Complexes of Ruthenium and Osmium Bertoli M., *Goussev D.G., $Bertoli M.
17:40 01834 Iron(III) Complexes of Diamine-bis(phenolate) Ligands as Potential Catalysts for C-C Cross-Coupling Reactions Chard E.F., *Kozak C.M.
17:40 01835 Agostic Ni-H-Si Interactions Via Si-C Bond Breaking and Si-H Bond Activation in Nickel Complexes With Unusual Oxidation States Beck R., *Johnson S.A.
17:40 01836 Palladium Catalyzed Formation of C(sp3)-C(sp2) Bonds From Boronic Acids and DDQ-Activated Toluene Derivatives Praetorius J.M., Luca O.M., *$Crabtree R.H.
17:40 01837 Bridged Diketiminate Zirconium Complexes El-Zoghbi I., *Schaper F.

Organometallic Reagents for Organic Synthesis - Graduate Student Poster Competition

17:40 01838 Synthesis, Characterisation and Catalytic Applications of POCOP Type Pincer Complexes of Nickel (II) Salah A., $Zargaian D.
17:40 01839 Synthesis, Characterization and Electrochemical Studies of New POCNimine-Type Pincer Complexes of Nickel Mougang-Soume B., $Zargarian D.
17:40 01840 Palladium-Catalyzed Multicomponent Synthesis of a-Aminostannanes Xu B., *$Arndtsen B.A.
17:40 01842 The Sequential Insertion of Imines and Carbon Monoxide with Neutral Palladium-Alkyl Complexes Kayser L.V., *$Arndtsen B.A.
17:40 01843 Mechanistic Study of the Sonogashira Reaction using PSI-ESI-MS Ahmadi Z., *McIndoe J.S.
17:40 01844 The Pauson-Khand Reaction Mechanism Investigation Luo J., *McIndoe S.J.
17:40 01845 Synthesis of Silver Nanoparticles on Kaolinite Surface Under UV Irradiation *$Parvinzadeh M.
17:40 01846 Regioselectivity of Ruthenium-Catalyzed [2+2] Cycloadditions of 3-Aza-2-oxabicyclo[2.2.1]hept-5-enes With Unsymmetrical Alkynes Durham R., *$Tam W., Mandel J., Blanchard N.
17:40 01847 Utilization of Intramolecular Nicholas Reaction Towards the Synthesis of Dibenzocyclooctenes Djurdjevic S., *$Green J.R.
17:40 01848 Preparation of Benzo-fused Cycloheptadienynol Alcohol Co2(CO)6 Complexes via Intramolecular Nicholas Reactions Mehdi M., *$Green J.R.
17:40 01849 Synthesis and Reactivity of Functionalized a-Alkoxy Ylides and Applications Toward the Synthesis of Compounds of Medicinal Interest $Keskar K., *McNulty J.
17:40 01850 Group 4 N,O-Chelates Complexes. Expanding Substrate Scope in Catalytic Amine Synthesis Yim J.C.-H., $Schafer L.L.
17:40 01851 Synthesis of the Ginkgolide C Spirobicyclic Core by Au(I)-catalyzed Cyclizations Lapointe D., *$Barriault L.

Green Chemistry and Catalysis posters

17:40 01852 Development and Efforts Towards the Commercialization of Green Gemini Surfactants *Decker S.M., Chase P.A., Mariampillai B., $Marangoni D.G., Grindley T.B.
17:40 01853 Green Chemistry at AstraZeneca R&D Montreal: Focus on Solvent Selection Pourashraf M., Turcotte P., Wells A., Samson-Thibault F., Laplante M., Cantin L.D., Walpole C., Tomaszewski M.J.
17:40 01854 Poly (Vinyl Alcohol)-graft-poly (Ethylene Glycol) Resins and Their Use in Solid Phase Chemistry and Catalysis Kassem T., Zelli R., Zhu X.X., *$Lubell W.D.

Green Chemistry and Catalysis - Graduate Student Poster Competition

17:40 01855 Chemical Conversion of Chitosan Under Green Conditions Omari K. W., *Kerton F.M.
17:40 01856 Noble Metal Nanoparticle - Ionic Liquid Tandem Systems for in-situ Catalysis Banerjee A., $Scott R.W.J.
17:40 01857 Condensation of Benzyl Amines to Imines and Dehydrative Etherification of Benzyl Alcohols in Phosphonium Ionic Liquids Kalviri H.A., *Kerton F.M.
17:40 01858 Efficient Aerobic Oxidation of Alcohols Using CuBr2 and a Series of a-y Pyridyl-imine Terminated Polydimethylsiloxane Ligands Hu Z., *Kerton F.M.
17:40 01859 Iron Catalysts for the Epoxidation of Olefins and C-C Cross Coupling Hasan K., *$Kozak C.M.
17:40 01860 Intramolecular Direct Alkylation of Unactivated Aromatic Rings Beaulieu L.-P. B., *Vallée F., $Charette A.B.
17:40 01861 A Novel Catalytic Desulfinylative Coupling of Aryl-sulfinates to Access Symmetric Biaryls Ortgies D.H., *Forgione P.
17:40 01862 New Opportunities in Domino Reactions and Gold Catalysis for Organic Synthesis Sow B., Bellavance G., De Leseleuc M., *Barriault L.
17:40 01863 Palladium-Catalyzed Aryl-Halide Carbonylation as a Route to Heterocycle Synthesis Quesnel J.S., Bontemps S., $Arndtsen B.A.
17:40 01864 Potassium tert-Butoxide Promoted Intramolecular Arylation *Sustac Roman D., Takahashi Y., $Charette A.B.
17:40 01865 Phosphine Functionalized Imidazolium Ionic Liquids as Stabilizers for Transition Metal Hydrogenation Nanoparticle Catalysts Stratton S.A., Luska K.L., *$Moores A.
17:40 01866 Selective Suzuki-Miyaura Coupling of a Substrate Incorporating Both an Aryl and an Alkyl Boronic Ester Hutchinson M., Holland A.M., $Crudden C.M.
17:40 01867 Iron(II)-catalyzed Asymmetric Mukaiyama Aldol Reaction in Aqueous Media Plancq B., *Ollevier T.
17:40 01868 Exploring Microbial Transglutaminase Acceptor Substrate Specificity; Applications for Biocatalysis *Gundersen M.T., Keillor J.W., $Pelletier J.N.
17:40 01869 Palladium Catalyzed Carboiodonation - A Novel, Atom Economical Coupling Reaction Howell J.K., Nicolaus N., Newman S.G., $Lautens M
17:40 01870 Simple Synthesis of Novel 2,2-Dialkyl-2,3-dihydrobenzofurans from Phenols and 2,2-Dialkylacetaldehydes Chou T.-Y., *$Jha A.
17:40 01871 Combined Surface Science and Organic Chemistry Study of Heterogeneous Asymmetric Catalysis Lafleur-Lambert R., Lavoie S., Demers-Carpentier V., Boukouvalas J., *$McBreen P.H.

Keith Fagnou Memorial Symposium - Graduate Student Poster Competition

17:40 01872 An Aminocarbonylation Route to b-Aminocarbonyl Motifs Markiewicz T., Clavette C., Gan W., Toderian A., *Beauchemin A.M.
17:40 01873 Synthesis of Substituted Imidazolinones via a Cationic Gold(I)-mediated Intramolecular Cyclization Proulx C., *$Lubell W.D.

Natural Products Chemistry posters

17:40 01874 Chemical Synthesis of a Series of 3-substituted Derivatives of 16b-(m-carbamoylbenzyl-estradiol) as Non Estrogenic Steroidal Inhibitor of 17b-hydroxysteroid Dehydrogenase Type 1 *Maltais R., Ayan D., Roy J., $Poirier D.
17:40 01875 Bioactive Natural Products from Matricaria chamomilla Shoqafi A.H., *$Ata A.
17:40 01876 Phytochemical Studies on Buxus macowanii Lam C.W., *$Ata A.
17:40 01877 Cyclic Iminium-Ion Dienophiles in Diels-Alder Reactions and Their Application Towards the Synthesis of Spiroimine-Containing Natural Products Marcoux D., Speed A.W.H., Bindschädler P., *$Evans D.A.
17:40 01878 Antioxidant Activity of Polar Fraction from Flax Oil Sharav O., *Owiti D.P.O.
17:40 01879 Influence of the Drying Method on the Yield of Essential Oil in Leaves of Pistacia lentiscus $Boualeg K., *Nouri S., Khaldi A.

Natural Products Chemistry - Graduate Student Poster Competition

17:40 01880 Multiple Electrophilic Aromatic Substitution Reactions of Phloroglucinol in the Total Synthesis of Biologically-Active Natural Products and Analogues Campbell M.K.H., $Wilson P.D.
17:40 01881 An Oxidative Prins-Pinacol Tandem Process and its Application to the Synthesis of (-)-Platensimycin Beaulieu M.A., Sabot C., Guérard K.C., *$Canesi S.
17:40 01882 Studies Towards the Total Synthesis of Eleutherobin Mowat J., $Britton R.
17:40 01883 "Aromatic Ring Umpolung", a Rapid Access to the Main Core of Several Natural Products $Guerard K.C., Sabot C., Beaulieu M.A., Giroux M.A., *Canesi S.
17:40 01884 Synthetic Studies Towards Palau'amine: Synthesis of trans-fused 5,5-Ring Systems Rivalti D., *$Gleason J.L.
17:40 01885 A Synthetic Approach Towards Natural Compounds Containing a Tetrahydroxanthone Structural Subunit Castillo-Contreras E.B., $Dake G.R.
17:40 01886 Concise and Stereoselective Synthesis of Pyrrolidine-Containing Natural Products Draper J.A., $Britton R.
17:40 01887 Towards a Total Synthesis of (-)-Amphidinolide K Campbell N.E., $Sammis G.M.
17:40 01888 Total Synthesis of Hodgsonox Lévaray N., Lebel H.
17:40 01890 Progress Towards a Formal Synthesis of Triptolide Schwantje T.R., Barriault L.
17:40 01891 Studies Toward the Total Synthesis of Haterumalides and Biselides Kang B., $Britton R.
17:40 01892 Towards the Enantioselective Synthesis of (1R, 1³R)-cycleanine Valluru G.K., *Georghiou P.E.
17:40 01893 Synthesis and Biological Evaluation of a Natural Lantibiotic Lacticin 3147 *Chan A.S.H., Liu W., Liu H., Cochrane S., $Vederas J.C.
17:40 01894 Studies Towards the Total Synthesis of Platensimycin Chen P.S.K., $Wilson P.D.
17:40 01895 Enantioselective Synthesis of a-Quaternary Amino Acid Derivatives Iosub V., *Back T.G.
17:40 01896 A Convergent Total Synthesis of Peloruside A *Speed A.W.H., Welch D.S., Moniz G.A., Reichelt A., Ho S., $Evans D.A.
17:40 01897 Towards a New Enantioselective Methodology of Allocolchicinoïds Cardinal S., Boudreault P., *Voyer N.

Organic Synthesis: Stereocontrol posters

17:40 01898 Organocatalytic Synthesis of Natural Products *$Withey J.M.
17:40 01899 Short Synthesis of Benzo[1,2,5]triazepin-4-ones via Intramolecular SNAr Substitution Jin S., St-Jean O., Santhakumar V., Tomaszewski M.
17:40 01900 Site-Selective Metal-Catalyzed Reaction of N-Bis(trimethylsilyl)methyl a-diazoamides. Synthesis of rac-Allokainic acid Zhang B., *Wee A.G.H.
17:40 01901 Synthesis and Antimalarial Activity of Chalcones and Thiophosphinic Acids Derivatives $Tazoo D., *Bohle D.S., Dalton J.P., Oniga O., Dongo E., Chua Z.
17:40 01902 Enantioselective Functionalization of Aldehydes using Chiral Secondary Amines as Catalyst Franke P.T., *$Jørgensen K.A., Lautens M.

Organic Synthesis: Stereocontrol - Graduate Student Poster Competition

17:40 01903 Organocatalytic Asymmetric Direct Vinylogous Aldol Reactions of 2-Furanone Paul E.K., *$Pansare S.V.
17:40 01904 Tandem Palladium-Catalyzed b-Carboelimination/Oxidative Heck Reaction for the Synthesys of a-Substituted-Z-chalcones Rosa D., *$Orellana A.
17:40 01905 Development of New Chiral Catalysts for the Iodine(III)-mediated Enantioselective a-Tosyloxylation of Ketones Guilbault A.-A., *$Legault C.Y.
17:40 01906 Towards the Total Synthesis of (-)-Cylindrocyclophane F Using a Cyclopropane-Based Approach $Goudreau S.R., Azzi S., *Charette A.B.
17:40 01907 Synthesis of Substituted Hydronaphthalenes Via Diastereoselective Friedel-Crafts Tsoung J., *Kramer K., $Lautens M.
17:40 01909 Enantioselective Synthesis of (+)-2-epi-deoxoprosopinine Annadi K., *Wee A.G.H.
17:40 01910 The Cross Coupling of Secondary Boronic Esters with Retention of Stereochemistry Glasspoole B.W., $Crudden C.M.
17:40 01911 Functionalization of 1,2-disubstituted Iodocyclopropanes *Schneider J.F., Beaulieu l.-P. B., $Charette A.
17:40 01912 Aldol Couplings of Chiral Fragments With Kinetic Resolution: Scope and Limitations Kazemeini A., *Ward D.E.

Modern Physical Organic Chemistry posters

17:40 01913 Synthesis, Thermodynamic and Kinetic Studies of Novel Diarylamine Antioxidants Hanthorn J.J., Valgimigli L., *$Pratt D.A.
17:40 01914 The Formation of Cholesterol-Derived Carbonyls From Cholesteryl 7-Hydroperoxide and 5-Hydroperoxide Lynett P.T., $Pratt D.A.
17:40 01915 Synthesis of Pyri(mi)dinol Adducts of BODIPY: Highly Reactive Off/On Fluorescent Antioxidant Indicator Yang J., *$Pratt D.A.

Modern Physical Organic Chemistry - Graduate Student Poster Competition

17:40 01916 Computational Studies of the Photo-induced Degradation of Lignin Model Compounds Zhang L., Peslherbe G.H., *Muchall H.M.
17:40 01917 Selective Anion Receptors Composed of Hydrogen and Halogen Bonding Groups Chudzinski M., McClary C., *Taylor M.S.
17:40 01918 Just Add Salt: A Photochemist's Synthesis for Fluorescent Organic Nanoparticles Mooi S.M., *Heyne B.
17:40 01919 Redox Chemistry of Selenenic Acids Presseau N.C., $Pratt D.A.
17:40 01920 Chiral Crystallization and Asymmetric Amplification of Diphenyl Disulfide McLaughlin D.T., Leung Y.H., *Cuccia L.
17:40 01921 Meso-formyl Bodipy Dyes: Sensitive Fluorescent Sensors for Nucleophilic Addition Studies Greene L.E., *Krumova K., $Cosa G.
17:40 01922 A Computational Investigation of Nitrilimine Formation and Cycloaddition Reactions Mehrpajouh S., Peslherbe G.H., *Muchall H.M.
17:40 01923 Supported Au Nanoparticles as Diels-Alder Catalysts $Marquez-Soto D., González-Béjar M., Hallett-Tapley G., Netto-Ferreira J.C., *Scaiano J.C.
17:40 01924 Laser Flash Photolysis of Diphenylgermylene (GePh2) with a Series of Alkenes in Hexanes Solution Saeidi Hayeniaz Y., *Leigh W.J., Chitnis S.

Supramolecular Materials - Graduate Student Poster Competition

17:40 01925 Synthesis and Characterization of Conjugated Poly (phenylene ethynylene)s as Selective Fluorescence "Turn-on" Sensors for Metal Ions Pourghaz Y., Dongare P., Thompson D.W., *Zhao Y.
17:40 01926 Development of New Supramolecular Hosts for the Immobilization of Pristine C60 on Surfaces Giguère J.-B., *Morin J.-F.
17:40 01927 Design of Novel Antimicrobial Contact Active Quaternary Ammonium Compounds for Grafting onto Metal Surfaces $Porosa L., Foucher D., Wolfaard G.
17:40 01928 Nucleobase-templated Polymerization: From DNA to Synthetic Polymers Dai Z., Ussing B., Bazzi H., *$Sleiman H.
17:40 01929 Synthesis and Investigation of the Liquid Crystalline Properties of 1,2:3,4-Dibenzanthracene Derivatives Paquette J., Yardley C., Psutka K., Cochran M., *$Maly K.E.
17:40 01930 Soluble n-type Thiadiazole Oxides: Synthesis and Supramolecular Chemistry *Keller S.N., Linder T., $Sutherland T.C.
17:40 01931 The Synthesis and Surface Study of [2]Pseudorotaxane Self Assembled Monolayers Bolla M.A., Loeb S.J., Carmichael T.B.
17:40 End of Session


Wednesday AM

OR4516c

Natural Product Chemistry (joint with BM13)

Organizer(s) - C. Spino
Chair(s) - Claude Spino

08:00 01932 Boron-Diol Interactions as the Basis for the Regioselective Functionalization of Carbohydrate Derivatives Lee D., *$Taylor M.S.
08:20 01933 Identification of Bioactive Natural Products from Medicinally Important Plants *$Ata A.
08:40 01934 The Alkyne Strategy for the Synthesis of Bioactive Targets Trost B.M.
09:20 01935 Towards the Synthesis of Caloundrin B Becerril-Jimenez F., *$Ward D.E.
09:40 01936 Oxidative Spirocyclization Routes Towards the Sawaranospirolides: Synthesis of Ent-sawaranospirolides C and D Withey J.M.
10:00 Coffee Break
Alfred Bader Award Lecture

10:20 01937 Approaches to Natural and Unnatural Oxacyclic Compounds West F.G.
11:00 01938 Progress Towards the Total Synthesis of Securinol B Using a Strategy of Sequential Nucleophilic Cyclizations onto an Activated Amide Dupuis M., Larouche-Gauthier R., *Bélanger G.
11:20 01939 Progress Towards a Synthesis of Vescalin Mayer M.-E., $Collins S.K.
11:40 01940 Biosynthesis of Isoprene Units: On the Characterization of the Reduction Steps in the MEP Pathway in Plants and Bacteria *Rohmer M., Toulouse J.
12:20 End of Session

OR7511b

Carbohydrates and Glycobiology (joint with BM6)

Organizer(s) - S. Sato; T. Lowary; D. Jakeman
Chair(s) - David Jakeman

08:00 See BM6.

12:20 End of Session

OR3513d

Organometallic Reagents for Organic Synthesis (joint with IN4)

Organizer(s) - S. Collins; B. Arndtsen
Chair(s) - Arndtsen

08:00 01941 Exploiting P,N "DalPhos" Ligands in Challenging Metal-Catalyzed C-N and C-C Bond-Forming Reactions *$Stradiotto M
08:40 01942 Catalytic C-H Bond Stannylation: A New Regioselective Pathway to C-Sn Bonds via C-H Bond Functionalization *Johnson S.A., Doster M.E., Hatnean J.A.
09:00 01943 Iron(II) Carbonyl Complexes with Aryl Functionalized Tetradentate P-N-N-P Ligands: Synthesis, Characterization and Catalysis Sues P.E., Mikhailine A.A., Lough A.J., *$Morris R.H.
09:20 01944 Radical Cycloalkylation of Propargyltitanium(III) Complexes Bauer R.C., Gauthier J., Morita M., Quesnel J.S., Stryker J.M.
10:00 Coffee Break
10:20 01945 Pt(II) Catalyzed C-F Activation of Polyfluoroarenes Keyes L., *$Love J.A.
10:40 01946 Negishi Cross-Coupling of Secondary Alkylzinc Halides with Aryl/Heteroaryl Halides Using PdPEPPSIIPent Calimsiz S., *$Organ M.G.
11:00 01947 Correlating Metathesis Performance with Catalyst Turnon, Speciation and Deactivation: A Multi-Method Approach *Fogg D.E.
11:40 01948 Hydroaminoalkylation with Amidate Complexes. Catalyst Development for the Synthesis of Chiral Amines and N-Heterocycles Schafer L.L.
12:20 End of Session

OR9511f

Supramolecular Materials (joint with MT2)

Organizer(s) - H. Sleiman; A. Schmitzer
Chair(s) - Andreea Schmitzer; Steve Loeb

08:00 See MT2.

12:20 End of Session


Wednesday PM

OR10513d

General Session

Organizer(s) - J.L. Gleason; H. Lebel
Chair(s) - F. Hof

13:40 01949 Negishi Cross Coupling of Vinylzincs with Aryl Triflates. A Friedel-Crafts Equivalent for the Regioselective Synthesis of Polysubstituted Acetophenone Derivatives Hurst T.E., da Silva A.J.M., *$Snieckus V.
14:00 01950 Highly Chemoselective and Controlled Conversion of Secondary Amides to Ketones Bechara W.S., Pelletier G., *Charette A.B.
14:20 01951 The Recognition Properties of Carboxylic Acid Bioisosteres: Anion Recognition by Tetrazoles, Aryl Sulfonamides and Acyl Sulfonamides Pinter T., $Hof F.
14:40 01952 Mild and Selective Boronic Acid Catalyzed 1,3-Transposition of Allylic Alcohols and Meyer-Schuster Rearrangement of Propargylic Alcohols Lejkowski M., Zheng H., *$Hall D.G.
15:00 01953 Photochemical Synthesis of Novel Helical Aromatic Compounds Vlassova A., Hernandez-Perez A.C., $Collins S.K.
15:20 01954 Pd-PEPPSI-IPent, a Highly Reactive Pre-Catalyst for Carbon-Sulfur Coupling Sayah M., *$Organ M.G.
15:40 Coffee Break
16:00 01955 Photochemical Modification of Gold Nanoparticles (Au-NP) via Nitrene Insertion Reactions Snell K.E., *Workentin M.S.
16:20 01956 Umbrella Thread as a New Membrane Chloride Transporter: Towards a New Vehicle for Cyclic Drug Transport $Chhun C., *Schmitzer A.R.
16:40 01957 Synthesis of a New Family of Noncarcinogenic Estradiol Agonists as an Alternative to Hormone Replacement Therapy *Choueiri C., Asim M., Klonowska D., Wright J.S., Shadnia H., Katzenellenbogen J., Carlson K., Santhakumar V., $Durst T.
17:00 01958 Novel Chemical Transformations on Indolin-2-ones and Indoline-2-thiones *$Jha M.
17:20 01959 Copper Ferrite Nanoparticle Catalyzed Biginelli Condensation; Proof of Concept for a Novel Class of Magnetically Recoverable Catalysts Hudson R., Silverman J., *Li C.-J., $Moores A.
17:40 01960 Taking a Stroll Around Azaindoles: The peri-Metalation Approach towards Polysubstituted Azaindoles David E., Toutov A., Schneider C., *$Snieckus V.
18:00 01961 An Investigation of the Synthesis and Optical Tunability of Copper (I) Compounds Glover L.A.M., Ma G., *$Cavell R.G., Veinot J.G.C.
18:20 End of Session

OR3516c

Organometallic Reagents for Organic Synthesis (joint with IN4)

Organizer(s) - S. Collins; B. Arndtsen
Chair(s) - Collins

Clara Benson Award Lecture

13:40 01962 Challenging the Suzuki-Miyaura Reaction: The Preparation of Novel Organic Structures through the Use of Chiral Organoboronic Esters *$Crudden C.M.
14:20 01963 Palladium and Rhodium Mediated Transformations *$Lautens M.
15:00 01964 C-H vs. C-C Bond Activation of Acetonitrile and Benzonitrile via Oxidative Addition: Rhodium vs. Nickel, Cp* vs. Tp', and PMe3 vs. CNR Evans M.E., Tanabe T., Li T., Jones W.D.
15:40 Coffee Break
16:00 01965 Frustrated Lewis Pairs: New Strategies for Catalysis and Synthesis *$Stephan D.W., Geier S., Dureen M., Mahdi T., Zhao X.
16:40 01966 Chemoselective Catalytic Reduction of Nitriles, Pyridines, and Acid Chlorides Gutsulyak D.V., *$Nikonov G.I.
17:20 01967 A Convenient Class of Acyloxyboronates as Protecting Groups for Boronic Acids in Chemoselective Cross-Coupling Chemistry Hirani N.N., *$Hall D.G.
17:40 01968 Mechanism of Catalytic Cyclohydroamination by Zirconium Salicyloxazoline Complexes Allan L.E. N., Gott A.L., Clarkson G.J., Fox D.J., *Scott P.
18:00 End of Session

OR9511f

Supramolecular Materials (joint with MT2)

Organizer(s) - H. Sleiman; A. Schmitzer
Chair(s) - Cornelia Bohne; James Wuest

13:40 See MT2.

18:00 End of Session

OR5511b

Organic Synthesis: Stereocontrol

Organizer(s) - J.L. Gleason; H. Lebel
Chair(s) - M. Gravel; M. Lautens

13:40 01969 Total Synthesis (?) of Amphidinolide C Morra N.A., $Pagenkopf B.L.
14:00 01970 Towards the Total Synthesis of Spiro-Prorocentrimine *Speed A.W.H., Bindschaedler P., Marcoux D., Juhl M.V., Borg G., Pero J., Chiu A., Brandl T., $Evans D.A.
14:20 01971 Stereoselective Routes to Octahydroindoles and Indolizidines for Applications in Alkaloid Synthesis *$Pansare S.V., Lingampally R., Dyapa R.
14:40 01972 Progress Towards Actinophyllic Acid Emmett M.R., $Kerr M.A.
15:00 01973 Marrying Iterative Synthesis to Cascading Radical Cyclizations for an Efficient Approach to Molecular Complexity *$Wulff J.E., Davies K.A.
15:40 Coffee Break
16:00 01974 Catalytic Enantioselective a-Tosyloxylation of Ketones : Mechanistic Insights *$Legault C.Y.
16:20 01975 Developpement of a Non-racemic Version of the Intramolecular [4+1]-Cycloaddition Between Electron-rich Carbenes and Different Dienes Dery M., $Spino C.
16:40 01976 Rhodium-Catalyzed Stereoselective Intermolecular Aziridination Spitz C., *Lebel H.
17:00 01977 Development and Application of New Au(I)-catalysts for Regioselective 5-exo-dig and 6-endo-dig Cyclizations Levesque P., Barabé F., Barriault L.
Merck Frosst Centre for Therapeutic Research Award Lecture

17:20 01978 Cleaving Unstrained Carbon-Carbon s Bonds as a Means to Transposing/Functionalizing sp3-Hybridized Carbon Centres *$Fillion E.
18:00 End of Session

UPC-O517ab

Undergraduate Student Poster Competition

17:40 01979 Synthesis and Study of Metallo-Receptors Based on the 1,2,3-Triazole Unit. Applications to Supramolecular Recognition Melan C., Wu N., Fleischel O., *$Petitjean A.
17:40 01980 Directed ortho Metalation Route Towards C-7 Functionalized Benzimidazoles Friedman A., Kitching M., Zhao Y., *Snieckus V.
17:40 01981 Dioxaborinanone Catalysed Friedel-Crafts Reactions of a,b-Unsaturated Ketones Hiebert R., *$McCubbin J.A.
17:40 01982 Development of a Green Catalytic Cross-Coupling Reaction of Aryl-Sulfinates in Aqueous Media De Cicco M., Ortgies D.H., *Forgione P.
17:40 01983 Dioxaborinanone Catalysed Rearrangement Reactions of Allylic Alcohols Voth S., *$McCubbin J.A.
17:40 01984 Investigation of Substituent Effects in Palladium-catalyzed Desulfinylative Cross-couplings of Aryl Bromides and Benzenesulfinate Rioux S., Ortgies D.H., Barthelme A., Aly S., Desharnais B., *Forgione P.
17:40 01985 Synthesis and Characterization of Novel PET Quenching Fluorophores for Boronic Acid-Based Saccharide Sensors McGregor N., *Pardin C., Skene W.
17:40 01986 Towards the Synthesis of Enantioenriched 2,6-Disubstituted Piperidines via a Negishi Cross-coupling on 2-Substituted Dihydropyridines Constantineau-Forget L., $Pelletier G., *Charette A.B.
17:40 01987 The Reactivity of Diarylgermylenes with Allyl Chloride Ochola J.
17:40 01988 Evaluation of Oxazinone Photosubtrates With a Chiral Hydrogen-Bonding Host: Progress Toward Intramolecular Enantioseletive Photoadditions Camasso N., Velissaris S., *$McLaughlin E.C.
17:40 01989 Fe-Pillared Clay Nanocomposite Improves Thermal Stability of Clay Particles *$Parvinzadeh M.
17:40 01990 No Title $Khatamian M., *Derogar M.
17:40 End of Session


Thursday AM

OR10511b

General Session

Organizer(s) - J.L. Gleason; H. Lebel
Chair(s) - J. Green

10:20 01991 Synthesis and Reactivity of a New Ynhydrazide Alkyne Class Beveridge R.E., *Batey R.A.
10:40 01992 Work Towards the Total Synthesis of Biselide A Morra B., $Pagenkopf B.L.
11:00 01993 Mechanistic Investigation of Palladium Catalyzed Decarboxylative Allylation of Sulfones Gill M.A., *Manthorpe J.M.
11:20 01994 Stereoselective Nickel-Catalyzed [2+2+2] Cycloaddition of Enynes and Arynes Candito D.A., *$Lautens M.
11:40 01995 Regioselective Multicomponent Pyrrole Synthesis via 1,3-Dipolar Cycloaddition of Tunable Mesoionic Heterocycles and Alkynes Morin M.S.T., St.-Cyr D.J., *$Arndtsen B.A.
12:00 01996 Novel Chiral C1-Symmetric NHC Cu(I) Complexes for Use in Catalysis Holtz-Mulholland M., $Collins S.K.
12:20 End of Session

OR3516c

Organometallic Reagents for Organic Synthesis (joint with IN4)

Organizer(s) - S. Collins; B. Arndtsen
Chair(s) - Collins

08:00 01997 Synthesis of Copper N-Heterocyclic Carbene Complexes via Decarboxylation and Application in Oxidative Coupling Reactions Le Gall T.A., $Collins S.K.
08:20 01998 Study Towards the Development of a General Gold(I)-Catalyzed 6-endo-dig Carbocyclization. Synthetic and Mechanistic Investigation Barabe F., McGee P., Bellavance G., *$Barriault L.
08:40 01999 Amphoteric Reagents in Organic Synthesis *$Yudin A.K.
09:20 02000 The Development of Superior Bis-phosphine Palladium(0)-based Catalyst Precursors for C-C, C-N and C-O Bond Forming Cross-Coupling Reactions *$Baird M.C., Fraser A.F., Jaksic B.E., Hull L.E., Jiang J.S.
10:00 Coffee Break
10:20 02001 Silicon-based Cross-Coupling Reactions: Methodology, Total Synthesis and Mechanistic Studies *$Denmark S.E.
11:00 02002 The Development of P,N-Ligands for Transition Metal-Catalyzed Transfer Hydrogenation and Cross-Coupling Reactions *Lundgren R.J., $Stradiotto M.
11:40 02003 Building a Better Understanding of Cross-Coupling Reactions *$Organ M.G., Valente C., Hadei N., Sayah M., Hoi K.H., Çalimsiz S., Achonduh G.T., Hunter H.N., Blagojevic V., Patschinski P., Avola S., Bohme D.K.
12:20 End of Session

OR9511f

Supramolecular Materials (joint with MT2)

Organizer(s) - H. Sleiman; A. Schmitzer
Chair(s) - Hanadi Sleiman; Dipankar Sen

08:00 See MT2.

12:20 End of Session

OR5511b

Organic Synthesis: Stereocontrol

Organizer(s) - J.L. Gleason; H. Lebel
Chair(s) - J. Wulff

08:00 02004 Enantioselective Total Synthesis of Some Alkaloids Containing Tetrahydroisoquinoline Core Units Zein A.L., *Georghiou P.E.
08:20 02005 Synthesis of Steroidal Azaspirolactones and Cyclic Carbamates at Position 3 of Androsterone Djigoué G.B., Poirier D.
08:40 02006 Development and Application of Catalysis Reactions for Aliskiren Synthesis and Analogs Chenard E., Guesné S., *Hanessian S.
09:00 02007 Expanding the Scope of Palladium-Catalyzed Reactions of Tertiary Alcohols Chtchemelinine A., Rosa D., Schweinitz A., *$Orellana A.
09:20 02008 Synthesis and Use of Diaminocyclopropenylidenes in Umpolung and Nucleophilic Catalysis Wilde M. M. D., *$Gravel M.
10:00 End of Session


Thursday PM

OR10511b

General Session

Organizer(s) - J.L. Gleason; H. Lebel
Chair(s) - J. Boukouvalas

14:40 02009 Synthesis of Monofluoroalkenes from 3,3-Difluoropropenes Bergeron M., Johnson T., *Paquin J.-F.
15:00 02010 Synthesizing EP4 Agonist-Bisphosphonate Conjugates for the Treatment of Osteoporosis Arns S., *$Young R.N., Morshed M.M.
15:20 02011 Photoinduced Coalescence of AuNP in Halogenated Solvents Hadadpour M., *Workentin M.S.
15:40 Coffee Break
16:00 02012 Chemoselective Catalytic C-O Activation. Construction of Polyarylated Fluorenones via Ru- and Pd-Catalyzed Suzuki Cross-Coupling Reactions da Silva A.J.M., Schneider C., $Snieckus V.
16:20 02013 Development and Application of New Synthetic Methods for the Preparation of Bioactive Compound Libraries *$Capretta A.
16:40 02014 Oligo-1,8-pyrenylenes Williams K.L.M., Venkataramana G., *Bodwell G.J.
17:00 02015 Synthesis of Fused 1,2,3-Triazoles: C-H Bond Functionalization in One-Pot Catalysis Panteleev J., Geyer K., Schulman J.M., *$Lautens M.
17:20 02016 Incorporating Tröger's Bases as Rigidifying Elements in Biomimetic Aromatic Cage Molecules Whiting A.L., Dubicki K.I., *$Hof F.
17:40 02017 Reactivity of Unsymmetrical Verdazyl Radicals Bancerz M., $Georges M.K.
18:00 02018 Dehydrogenation of Alcohols Catalyzed by Pincer Complexes of Osmium and Rhenium Spasyuk D.M., *$Goussev D.G.
18:20 End of Session

OR3516c

Organometallic Reagents for Organic Synthesis (joint with IN4)

Organizer(s) - S. Collins; B. Arndtsen
Chair(s) - Arndtsen

14:40 02019 Bicatalytic Allylation- Cross Metathesis Approach to c-Carbonyl Cation Equivalents Henkie J.R., Dhaliwal S., *$Green J.R.
15:20 02020 Chromium-Catalyzed Radical Cyclization of Bromo and Chloro Acetals MacLeod K.C., *Smith K.M.
15:40 Coffee Break
16:00 02021 Investigation of the Ruthenium Catalyzed Homo Diels-Alder [2+2+2] Cycloaddition Between Alkynyl Phosphonates and Bicyclic Alkenes $Kettles T.J., *Tam W.
16:20 02022 Zirconium Complexes for Catalytic Hydroamination Yonson N., $Schafer L.L.
16:40 02023 Synthesis and Reactivity of Diphosphido Pincer Ligands Ritch J.S., Julienne D., Grisnich G., Vathracoulis S., *Hayes P.G.
17:00 02024 New Mesoionic Carbenes (MICs): Synthesis and Applications of Highly Stable 1H-1,2,3-triazol-5-ylidenes *Bouffard J., Guisado-Barrios G., $Bertrand G.
17:20 02025 Rhodium-catalysed Triple Domino Synthesis of Bicyclo[2.2.2]lactones. Novel Building Blocks for the Ergoline Alkaloids Boyer A., *$Lautens M.
17:40 02026 Non-Carbonyl-Stabilized Rhodium Carbenoid C-H Insertion of N-Aziridinylimines Mahoney S.J., *$Fillion E.
18:00 End of Session

OR9511f

Supramolecular Materials (joint with MT2)

Organizer(s) - H. Sleiman; A. Schmitzer
Chair(s) - John Sherman; Normand Voyer

14:40 See MT2.

18:00 End of Session


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