94th Canadian Chemistry Conference and Exhibition


Inorganic Chemistry

Monday AM

IN8510d

General Session

Organizer(s) - C. Reber
Chair(s) - C. Reber

08:00 00968 The Catalytic Reactivity of Organometallic Diamido-Actinide Complexes Hayes C.E., *$Leznoff D.B.
08:20 00969 Unique Bonding and Reactivity in non-Cp Organolanthanide Complexes Johnson K.R.D., $Hayes P.G.
08:40 00970 Synthesis and Characterization of Novel Hydroxyamidinate Cobalt Complexes Cibian M., Derossi S., *Hanan G.
09:00 00971 Synthesis of Cyclopentadienyl Chromium Imido Complexes Zhou W., *Smith K.M.
09:20 00972 The Nitrotetrazolate-2N-Oxide Anion: New Energetic Materials and Chemistry Göbel M., Karaghiosoff K., *Klapötke T.M., Piercey D.G., Stierstorfer J.
09:40 00973 Unusual Reactivity of Bis(trimethylphosphine)acetylacetonatoRh(I) Towards Diynes: A Route to Luminescent Organometallic Compounds $Thibault M.-H., Tay M.G., Steffen A., Bastanov A.S., Beeby A., *Marder T.B.
10:00 Coffee Break
10:20 00974 The Electronic Structure of Ruthenium Bis(b-diketonate) Complexes of Redox-active Verdazyl Radicals, as a Function of Oxidation State - a DFT Analysis McKinnon S.D.J., Patrick B.O., Lever A.B.P., Hicks R.G.
10:40 00975 Synthesis, Characterization, and DFT Investigation of a Series of Multi-Nuclear Ruthenium Complexes Incorporating Non-Innocent Ligands Kalinina D., Dares C., Potvin P.G., *$Lever A.B.P.
11:00 00976 Electronic and Steric Control of Dioxygen Binding in Transition Metal Complexes: Exploration of Factors that Favour Formation of Singlet Dioxygen Adducts Covelli D., *$Kennepohl P.
11:20 00977 Structural Basis for the Vapochromic Response of a Series of Platinum(II) Salts *Connick W.B., Taylor S.D., Muldoon A.M., Norton A.I., Krause J.A.
11:40 00978 Low-power Noncoherent Photon Upconversion for the Development of Dye Sensitized Solar Cells Sugunan S.K., Paige M.F., Steer R.P.
12:00 00979 Excited State Mixed Valence Zink J.I.
12:20 End of Session

IN5510b

Main Group Chemistry: Fundamentals and Applications

Organizer(s) - P. Ragogna; A. Dyker
Chair(s) - Paul Ragogna

08:00 00980 Applications of Early Transition-Metal Chemistry to the Synthesis of Main Group Compounds Velian A., Tofan D., Cossairt B.M., $Cummins C.C.
08:40 00981 Applications of Hexacoordinated Phosphorus(V) Anions Siu P.W., $Gates D.P.
09:00 00982 Stannylphosphonium Salts MacDonald E.P., Doyle L., *Burford N., Decken A., McDonald R.
09:20 00983 Voltammetry and In Situ EPR Spectroelectrochemistry of Congested Phenylchalcogenides peri-Substituted on Naphthalene Rings *$Boeré R.T., Roemmele T.L., Aschenbach L.K., Randall R.A.M., Knight F.R., Bühl M., Slawin A.M.Z., Woollins J.D.
09:40 00984 Pnictenium Cations: Redox Reactions and the Freedom to Choose the Counteranion Brazeau A.L., *$Ragogna P.J.
10:00 Coffee Break
10:20 00985 Donor-Acceptor Stabilization of Heavy Group 14 Element Hydrides (EH2 and H2EEH2; E = Si, Ge or Sn) *$Rivard E., Al-Rafia S.M.I., Liew S.K., Malcolm A.C., Ferguson M.J., McDonald R.
11:00 00986 Pressure-induced Enhancement of the Magnetic Ordering Temperature of a Thiazyl Radical: A Magneto-structural Correlation *$Rawson J.M., Thomson R.I.
11:20 00987 The Influence of Intramolecular Secondary Bonding on the Chemical and Spectroscopic Properties of Organo-Chalcogen Compounds Elder P.J.W., *Vargas-Baca I.
11:40 00988 Phosphorus-centered Cations in Synthesis Echterhoff A.K.C., Feldmann K.-O., Henne F.D., Holthausen M.H., Schulz S., *$Weigand J.J.
12:20 End of Session

IN1511c

Symposium in Honour of John Harrod

Organizer(s) - I.S. Butler; D. Zargarian
Chair(s) - Ian Butler

08:00 00989 High-pressure Infrared and Raman Spectroscopy: Mechanochemistry of Organosilicon Compounds *$Butler I.S.
08:20 00990 Rhodium: Increasingly Expensive But Even Richer in Chemistry James B.R.
09:00 00991 Vibrational Spectroscopy of Ternary Metal Hydride Salts: Ca2RhH5, Ca2IrH5 and Sr2IrH5 Barsan M.M., Butler I.S., *Gilson D.F.R., Moyer Jr.,R.O., Wu H., Udovic T.J.
09:20 00992 Development of New Classes of Metal Catalyzed Coupling Reactions *$Arndtsen B.A.
10:00 Coffee Break
10:20 00993 High Surface Area Metal Structures by Citrate Surfactant Reduction *$Brook M.A., Gonzaga F.
11:00 00994 Crystal to Crystal Transformation and Small Molecule Activation of Rhodium Bis(N-Heterocyclic Carbene) Complexes Keske E.C., Zenkina O.V., Wang R., $Crudden C.M.
11:20 00995 The Chemistry and Properties of T8, T10 and T12 {[RSiO1.5 ]8,10,12} Silsesquioxanes *$Laine R.M.
12:00 00996 Boro- and Alumino-hydride Complexes in Polymerization Catalysis *$Collins S.
12:20 End of Session


Monday PM

IN8510d

General Session

Organizer(s) - C. Reber
Chair(s) - P.V. Radovanovic

13:40 00997 Supramolecular Chemistry Applied to Nanosensor Design Based on Metal-Enhanced Fluorescence Bracamonte A.G., Brouard D., Magnan F., L.-Viger M., *$Boudreau D.
14:00 00998 Shape Design and Property Alterations of Aurocarbon Core-shell Species *$Naumkin F.Y.
14:20 00999 Size Control in the Synthesis of Thiolate-Protected Gold Nanoparticles *Goulet P.J.G., $Lennox R.B.
14:40 01000 Synthesis of Nanostructured NiS2 by Ultrasonic Spray Pyrolysis $Mondal D., Villemure G., *Song C., Li G., Zhang J., Hui R., Fairbridge C., Chen J.
15:00 01001 From Molecule to Materials: Crystalline Superlattices of Nanoscopic CdS Levchenko T.I., Kübel C., *Corrigan J.F., Huang Y.
15:20 01002 Isocyano Analogues of the Classic Unsaturated Cobalt Carbonyls *$Figueroa J.S., Margulieux G.W., Weidemann N., Carpenter A.E.
15:40 Coffee Break
16:00 01003 Tunable Dual Emission in Doped Semiconductor Nanoparticles Beaulac R., Vlaskin V.A., Janßen N., *$Gamelin D.R.
16:20 01004 Development of New Ferroelectric Materials from La(Zn1/2Ti1/2)O3 - Bi(Zn1/2Ti1/2)O3 - PbTiO3 Ternary Solid Solution Belan R.A., Tailor H.N,, *$Ye Z.-G.
16:40 01005 The Effect of High-Pressure on Molecular Magnetism Prescimone A., *$Brechin E.
17:00 01006 In Situ High Pressure Study of ZIF-8 by FTIR Spectroscopy Hu Y., Huang Y.N., Song Y.
17:20 01007 Pressure and Temperature Dependent Luminescence Study of Cyclometalated Pt(II) Complexes Rodrigue-Witchel A., Reber C.
17:40 End of Session

IN5510b

Main Group Chemistry: Fundamentals and Applications

Organizer(s) - P. Ragogna; A. Dyker
Chair(s) - C. Adam Dyker

13:40 01008 The Chemistry of Si6R6 Isomers *Scheschkewitz D., Abersfelder K., White A.J.P., Rzepa H.S.
14:20 01009 Fundamental Insights from the Investigation of Complexes of Low Valent Tin with Multidentate Ligands Macdonald C.L.B.
14:40 01010 Development of Main Group Complexes for the Activation of CO2 and Related Heteroallenes Dickie D.A., $Kemp R.A.
15:00 01011 Synthesis and Coordination Chemistry of Cationic Lead(II) Thiolates *$Briand G.G., Decken A., Finniss M.C., Gordon A.D., Hughes N.E., Scott L.M.
15:20 01012 Recent Advances in the Reactivity of Low Valent Carbon and Phosphorus Centres *$Masuda J.D., Giffin N.A., Hendsbee A.D., MacDonald S.C.A, Keyes L.K., Roemmele T.L., Lumsden M.D.
15:40 Coffee Break
16:00 01013 A Luminescent Boron-Stabilized Enol: Catalytic Alkyne Hydration Assisted by Lewis Acid/Base Cooperativity Sun C., Lu J.-S., *$Wang S.
16:20 01014 Synthesis and Properties of Polyaminoboranes Prepared by Catalytic Dehydrocoupling of Amine-Boranes Robertson A.P.M., Staubitz A., Sloan M.E., Helten H., Vance J.R., *Manners I.
16:40 01015 Advances and Challenges in Catalytic Asymmetric Hydrogenations Using "Frustrated Lewis Pairs" Heiden Z.M., *Stephan D.W.
17:00 01016 Synthesis and Subsequent Reaction Chemistry of Germanium Hydrazides Brown Z.D., Fettinger J.C., $Power P.P.
17:20 01017 Activation of Hydrogen with Perfluoroarylboranes: Scope and Mechanism Piers W.E., Fan C., Houghton A.Y., Dutton J.L., Marwitz A., Parvez M., Tuononen H.M.
18:00 End of Session

IN1511c

Symposium in Honour of John Harrod

Organizer(s) - I.S. Butler; D. Zargarian
Chair(s) - Davit Zargarian

13:40 01018 Catalytic Dehydrocoupling/Dehydrogenation of Amine Boranes: Mechanisms and Applications Manners I.
14:20 01019 Some Developments in Organosilyl and Group 4 Metallocene Chemistry in Canada in the Post-Harrod Era *$Baird M.C., Sauriol F., Sonnenberg J.F., Chadder S.J., Dunlop-Brière A.F.
15:00 01020 Surprising Mechanisms of Action of Asymmetric Ketone Hydrogenation Catalysts *$Morris R.H.
15:20 01021 Strong Evidence for Iron Nanoparticles Catalyzing Asymmetric Transfer Hydrogenation Sonnenberg J.F., Morris R.H., Coombs N., Dube P., Prokopchuk D.E.
15:40 Coffee Break
16:00 01022 New Pathways in Metal-Mediated Transformations of Organosilicon Compounds *$Tilley T.D.
16:40 01023 The Coordination Chemistry of Borabenzene Revisited *$Fontaine F.-G., Barnes S.S., Légaré M.-A., Maron L.
17:00 01024 New Ru, Rh, and Ir Complexes Supported by Hemilabile PSiN Mixed Donor Tridentate Silyl Ligands Ruddy A.J., *$Turculet L.
17:20 01025 Organometallic Chemistry with a Difference: Reactions in Water and in Ionic Liquids Chan T.H.
18:00 End of Session

INpos517abc

Poster Session

From 17:40 until 20:30

17:40 01026 The Synthesis, Characterization and Reactivity of Lanthanide Complexes with Carbazole-bis(oxazoline) Ligands Zou J., Berg D.
17:40 01027 Fungus on Your Wood? Try a Copper(I) Arylspiroboronate Ester Complex! Lee G.M., Vogels C.M., Decken A., Baerlocher F.J., *Westcott S.A.
17:40 01028 Iridium Arylspiroboronate Esters: Effective Precatalysts for the Hydroboration of Alkenes with Pinacolborane Lee G.M., Vogels C.M., Decken A., *Westcott S.A.
17:40 01029 Palladium Salicylaldimine Complexes Derived from 2,3-dihydroxybenzaldehyde Bowes E.G., Lee G.M., Vogels C.M., Decken A., Barnett D.A., *Westcott S.A.
17:40 01030 Studies on Synthesis, Characterization, Luminescence Properties and Biological Activity of Lanthanide Complexes with a Macroacyclic Schiff Base Ligand *$Taha Z., Ajlouni A., Faiq A.
17:40 01031 Raman Spectroscopy of Iron (II) Spin Crossover Complexes Rollet F.G., *Reber C.
17:40 01032 Optical Spectroscopy for Some Organometallic Complexes Intissar M., Reber C.
17:40 01033 Frustrated Lewis Pairs with Bidentate Lewis Acids: CO2 Activation and More Dömer J., Stephan D.W.
17:40 01034 Stabilized 4- and 5-Coordinate Polystannanes Khan A., *$Foucher D.A.
17:40 01035 Exploring Electronic Behaviour in N-Heterocyclic Organometallic Complexes *Poisson J., Wharf I., Bohle D.S., Barsan M.M., Gu Y., $Butler I.S.
17:40 01036 Ruthenium Piano-Stool Complexes Incorporating Novel Bis(N-pyrrolidinyl)alkylphosphines Beach M.T., Wang R., *$Spivak G.J.
17:40 01037 Hydrogenation of LiH/Al Catalyzed with TiN, TiMn2 and LaNi5 $Azenwi F.F., Langmi H.W., McGrady G.S.
17:40 01038 Death and Dying in Ru-Catalyzed Olefin Metathesis: Direct Studies of the Active Species under Catalytic Conditions Lummiss J., $Fogg D.E.
17:40 01039 Exchange Interactions in Mn2+-Doped Semiconductor Nanocrystals Beaulac R., *$Gamelin D.R.
17:40 01040 The Effect of High-Pressure on Molecular Magnetism Prescimone A., *$Brechin E., Parsons S.
17:40 01041 An Improved Route to the Second-Generation Grubbs Catalyst, RuCl2(H2IMes)(PCy3)(=CHPh) Reckling A., Lummiss J., $Fogg D.E.
17:40 01042 Synthesis and Phase Analysis of New Ferroelectric Ceramics and Single Crystals of Lead-Free (K0.5Na0.5)NbO3 (Bi0.5K0.5)TiO3 BaTiO3 Ternary System Wong J.Y.Y., *$Ye Z.-G.
17:40 01043 Iron/Aluminum Separation Using Polymer Enhanced Filtration $Nagy E., *Alex S.
17:40 01044 Twisting, Bending, Stretching: Strategies for Making Ferromagnetic [MnIII3] Triangles Inglis R., Papaefstathiou G.S., Wernsdorfer W., *Brechin E.K.
17:40 01045 Primary N-Nitroamide Acids and Their Transition-Metal Complexes Chua Z., *$Bohle D.S.
17:40 01046 Insights On Metallation of Pincer-Type Ligands by Nickel(II) Vabre B., *Ess D., $Zargarian D.
17:40 01047 Synthetic and Mechanistic Studies Related to the Development of Improved Iron Catalysts for Ammonia-Borane Dehydrogenation Rankin M.A., *$Baker R.T.

IN General - Graduate Student Poster Competition

17:40 01048 Half-Sandwich Rhodium(III) Complexes Featuring a Phosphine-Alane Ligand for the Stabilization of Rhodium and Aluminum Bound Ethylene p-Complexes Boudreau J., *$Fontaine F.-G.
17:40 01049 An Organometalic Approach to Single-Molecule Magnets Le Roy J., Jeletic M., *$Murugesu M.
17:40 01050 Structural and Magnetic Differences in Two Tetranuclear Dysprosium (III) Single-Molecule Magnets Lin P.-H., Korobkov I., Burchell T.J., Ungur L., *$Murugesu M., Chibotaru L.F., Wernsdorfer W.
17:40 01051 Early or Late?: Copper Salts and Oxovanadium Complexes for Selective Oxidation of Lignin Models *Díaz-Urrutia C., $Baker R.T., Sedai B.
17:40 01052 Novel Early Transition Metal Complexes Containing Sterically Bulky Bis(amido)silyl Ligands Lummis P.A., $Rivard E., Al-Rafia S.M. I, Liew S.J.-H., Ferguson M.J., McDonald R.
17:40 01053 Synthesis and Magnetic Properties of a Mononuclear, Cobalt(II) based Single Molecule Magnet Farghal A., Jurca T., Korobkov I., Murugesu M., Richeson D.
17:40 01054 Synthesis of Planar Chiral Complexes of Novel Phosphonium 1-Indenylides and a Study of Their Enantioselective Catalytic Properties Purdavaie K., $Baird M.C.
17:40 01055 Synthesis and Characterization of a Series of Ln(III) Compounds with Diamagnetic and Paramagnetic Ligands Fatila E.M., $Preuss K.E., Jennings M., Clerac R., Lough A.
17:40 01056 Oxygen- and Nitrogen-Group Transfers in Aryl-Nitroso Iron Complexes Habibian M., *$Ottenwaelder X.
17:40 01057 Assigning Transitions and Modeling Predicted Electronic Spectra for Inorganic Complexes Involving Innocent and Non-innocent Ligands Dares C., Fourner R., *$Lever A.B.P.
17:40 01058 Probing the Fate of Metathesis Catalysts Under Catalytically-relevant Conditions Blacquiere J.M., *Fogg D.E.
17:40 01059 Exploring the Strong Binding of Dinitrogen to Ruthenium Centers Higman C.S., Blacquiere J.M., $Fogg D.E.
17:40 01060 Selective Oxidative Additions and Functionalizations of Fluorinated Arenes with Ni(0) and a Nitrogen Ancillary Ligand Doster M.E., *Johnson S.A.
17:40 01061 Reactivity of a Ruthenium Formate Complex Ireland B.J., $Fogg D.E.
17:40 01062 Structural Variations in Rigid Pincer-Type NON Ligands for Highly Electropositive Metals Andreychuk N.R., $Emslie D.J.H.
17:40 01063 Uncovering New Reactivity Utilizing Frustrated Lewis Pairs Caputo C.B., $Stephan D.W.
17:40 01064 Towards the Synthesis of Late Transition Metal Complexes Featuring New CSiC Tridentate Silyl Carbene Ligands Weale M., *$Turculet L.
17:40 01065 The Synthesis and Application of Tridentate Phosphinimine Ligands in Group 8 Chemistry Brown C.C., $Stephan D.W.
17:40 01066 Examples of Spectroscopic Methods Used to Probe Organometallic Compounds Baslon V., Reber C.
17:40 01067 Exploiting Functional Group Containing Ligands for the Synthesis of Group 10 Pincer Complexes Sgro M.J., $Stephan D.W.
17:40 01068 Preparation and Reactivity of Terminal Group 3 Imido Complexes Chu T., $Piers W.E., Parvez M.
17:40 01069 A 3,6-Bis(2-pyridyl)pyridazine Complex of Dimethylplatinum(II): An Attempt at Bimetallic C-H Bond Activation *McCready M.S., $Puddephatt R.J.
17:40 01070 Mononuclear and Dinuclear Palladium and Nickel Complexes of Phosphinimine-based Tridentate Ligands Dahcheh F., Cariou R., $Stephan D.W.
17:40 01071 Towards Organometallic Platforms for Water Activation: arylPCP-Rh Complexes Riegel S.D., $Piers W.E., Masood P.
17:40 01072 Synthesis and Properties of Mn2+-Doped CdSe Nanoparticles from Cluster Precursors Nikkel B., *Eichhöfer A., $Corrigan J.F.
17:40 01073 Heterobimetallic Ru(II) Complexes Based on 2-(2'-pyridyl)indolyl and 2-(2'-pyridyl)benzimidazolyl Ligands Wang N., $Wang S.
17:40 01074 Coordination Chemistry of Indigo Derivatives *Nawn G., $Hicks R.G.
17:40 01075 Synthesis of Polyferrocenyl Stannanes Through a Pt Catalyzed Condensation Ward J., Al-Fouri T., Stanescu P., *$Foucher D.A.
17:40 01076 Reactivity of CO2 with Scandium b-diketiminato Supported Neutral, Cationic and Dicationic Bis-alkyls LeBlanc F.A., $Piers W.E., *Berkefeld A., Parvez M.
17:40 01077 A Novel PCP Iridium Complex for Bond Activation Burford R.J., $Piers W.E., Parvez M.
17:40 01078 Monomeric Platinum(II) Hydroxides Stabilized by Bulky a-Diimine Ligands Lohr T.L., Piers W. E., Parvez M.
17:40 01079 New Class of Triarylboron Electron-Transport Materials for Highly Efficient Blue PhOLEDs Varlan M., $Wang S.
17:40 01080 Synthesis and Structure of Chromium (III) Complexes of Amine-bis(phenolate) Ligands Belanger J.A., *$Kozak C.M.
17:40 01081 Frustrated Lewis Pairs as Ambiphilic and Amphoteric Ligands for Transition Metal Complexes Granville S.L., $Stephan D.W.
17:40 01082 An Azadipyrromethene Dye Derivative in Coordination Chemistry: Homoleptic M(II) Complexes Bessette A., Ferrera J., Bélanger F., $Désilets D., *Hanan G.S.
17:40 01083 Synthesis and Properties of a Highly-Energetic Compound Containing a Chain of Ten Nitrogen Atoms Klapötke T.M., Piercey D.G.
17:40 01084 Synthesis and Characterization of Novel Hydroxyamidinate Ligands and Their Metallic Complexes Cibian M., Langis-Barsetti S., *Hanan G.S.
17:40 01085 Characterization of Al-exchanged Clay Nanocomposites *$Parvinzadeh M.
17:40 01086 Physicochemical and Electrochemical Properties of New Redox Couples for Dye-Sensitized Solar Cells Brault V., Breau L., *$Marsan B.

Sympoisum in Honour of John Harrod posters

17:40 01087 Dimeric Rhodium Complexes with N-Heterocyclic Carbene Ligands Zenkina O.V., Keske E.C., Wang R., *Crudden C.M.

Sympoisum in Honour of John Harrod - Graduate Student Poster Competition

17:40 01088 The Synthesis and Characterization of Iron-Gold Core-Shell Nanoparticles Rak M.J., Moores A., Cirtiu C.M.
17:40 01089 Synthesis of Abnormal N-Heterocyclic Carbene CCC Pincer Ligands Keske E.C., $Crudden C.M.

Metal-catalyzed Polymerization posters

17:40 01090 Synthesis of Conjugated Polymers via Zirconium Metallacycle Transfer *$Kang L.
17:40 01091 A Powerful New Ruthenium Initiator for Living Ring-Opening Metathesis Polymerization: Precise, Ambient-Temperature Control, and Facile Removal Marleau-Gillette J., *Monfette S., $Fogg D.E.

Metal-catalyzed Polymerization - Graduate Student Poster Competition

17:40 01092 Side-chain Co(I) Polymers Featuring an Appended CpCoC4R4 Moeity Chadha P., Ragogna P.J.
17:40 01093 Lithium, Zinc and Group 4 Metal Complexes Supported by Amine-phenolate Ligands in Ring-Opening Polymerization of Lactide and e-Caprolactone Ikpo N., *Kerton F.M.
17:40 01094 Investigation of Multimetallic Li and Cr Complexes as Polymerization Catalysts Dean R.K., *$Kozak C.M.
17:40 01095 Bis(imino)pyridine Based Vanadium Catalysts in Vinyl Acetate Polymerization *$Shaver M.P., Perry M.R.
17:40 01096 Synthesis of Click Main-chain Bile Acid Polymers Ivanysenko O., *Zhu X.X.

Metallosupramolecular Assemblies posters

17:40 01097 Metal-Directed Self-Assembly of Macrocycles Laramee B., *K. Pal A.
17:40 01098 Relativistic Density Functional Study on Electronic Structure and Stability of An6O88+ Clusters and Related An(IV)-Oxygen Polyhedra, An=Th, U *Shamov G.A.
17:40 01099 Fe(III)-Ln(III) Calix(4)arene Clusters Sanz S., *Dalgarno S.J., $Brechin E.K.
17:40 01100 New Co-based Metal Organic Frameworks (MOFs) with Asymmetric Hcpt Ligand Aharen T., Habib F., Korobkov I., Kleiz F., $Murugesu M.
17:40 01101 Recipes for Enhanced Molecular Cooling *Hooper T.N., Evangelisti M., Langley S.K., Murray K.S., $Brechin E.K.
17:40 01102 Gradual Spin Crossover Behaviour in a Novel Linear Trinuclear Fe(II) Complex Cook C., Savard D., Enright G.D., Korobkov I., Burchell T.J., *$Murugesu M.

Metallosupramolecular Assemblies - Graduate Student Poster Competition

17:40 01103 Rhodium Amidinate Dimers as Hubs for Supramolecular Assemblies and Antennas Chartrand D., *Hanan G.S.
17:40 01104 Analysing the Physical Properties of Transition Metal and Lanthanide Thiocyanate Complexes Savard D., *Leznoff D.B.
17:40 01105 Nanocomposite Derived from Montmorillonite and Metallosupramolecular Polyelectrolyte: Modular Compounds for Electrorheological Fluids Geist M., Brede F., Boussois K., Rossignol S., Smith A., Peyratout C.S., *Kurth D.K.
17:40 01106 A Single Pot Synthesis for a Class of Palladium(II) Based Self-Assembly Tripathy D., *Debata N.B., $Chand D.K.
17:40 01107 Thio Appended Crown Ethers for Inverse Metal Organic Rotaxane Frameworks (i-MORF) Frank N.C., *Loeb S.J.
17:40 01108 Building Polynuclear Complexes with Double Headed Phenolic Oximes $Mason K., Chang J., Prescimone A., Schnack J., Tasker P.A., Carretta S., *Brechin E.K.
17:40 01109 Transition Metal Calixarene Complexes Taylor S.M., MacIntosh R.D., Evangelisti M., Dalgarno S.J., $Brechin E.K.
17:40 01110 Toward High Spin Polymetallic Complexes Containing Triarylamminium Radical-Cation Ligands Revunova K., *$Lemaire M.T.
17:40 01111 A Self-assembly Approach of Chromophores and Polyoxometalates Pal A.K., Santoni M.-P., Laramee B., Tremblay P.M., *Hanan G.S.

Main Group Chemistry: Fundamentals and Applications

17:40 01112 Synthesis, Characterization and Reactivity of Low Valent Tin Hydrides Knapp C.E., *$Power P.P.
17:40 01113 Characterization of New Trithionite Salts Bruna P.J., Grein F., *$Passmore J., Paulose T.A.P.
17:40 01114 X-Ray Crystal Structure of (C2H5)4N(SO2)Br Adduct, Reversible Uptake of SO2 Kumar A., $Passmore J., *McGrady G.S.
17:40 01115 A Newly Developed C1-bridged Phosphorus/Boron System: Application as a Frustrated LEWIS Pair Stute A., Kehr G., Fröhlich R., *Erker G.
17:40 01116 Preparation and Reactivity of 2-Amino-3-N-pyridinium-thiophenes: Precursors to Cyclic and Acyclic Thiazyls *Hayward J.J., $Rawson J.M.
17:40 01117 Bonding Properties of Seven-membered Carbocyclic Carbenes and Their Metal Complexes Peuronen A., Hänninen M. M., Moilanen J., *Tuononen H.M.
17:40 01118 Synthesis, Characterization, and Chemical Bonding of Alkali Metal Silyl Hydride Complexes: Tetrahedral vs Inverted Coordination *$Wolstenholme D.J., Landry M.J., McGrady G.S., Prince P.D., Steed J.W.
17:40 01119 N,C-Bound Phosphenium Cations: Reactivity Towards Small Molecules Gray P.A., *Ellis B.D.

Main Group Chemistry: Fundamentals and Applications - Graduate Student Poster Competition

17:40 01120 A Borabenzene Ditertbutylphosphine Ligand for use in Group 10 Metal Complexes Macha B., $Fontaine F.-G.
17:40 01121 The Effect of the Environment on the 125Te NMR Chemical Shift of Ditellurides Elder P.J.W., *Vargas-Baca I.
17:40 01122 Activation of Carbon Dioxide by Ambiphilic Molecules Courtemanche M.-A., *Boudreau J., $Fontaine F.
17:40 01123 Exploring the Chemical Bonding and Supramolecular Chemistry of Alkali Metal Dimethylamidoboranes $Flogeras J., Wolstenholme D.J., Decken A., *McGrady G.S.
17:40 01124 P-C Model Complexes and Polymers for Metal Sequestration Juilfs A., Gates D.
17:40 01125 Radical Anion Salts of a 1,2,5-Thiadiazolo-naphthoquinone Morgan I.S., $Preuss K.E., Jennings M., Clerac R.
17:40 01126 Investigating Allylindium Structure and Reactivity Allan C.J., *$Macdonald C.L.B.
17:40 01127 Tris(pentafluorophenyl)boron-Catalyzed Metal-Free Amine Racemization and Transfer Hydrogenation Farrell J.M., $Stephan D.W.
17:40 01128 Hydride Transfer from [HB(C6F5)3]-: Stepwise or Concerted Bailey A., *Webb J.D., Mosey N., $Crudden C.M.
17:40 01129 Triarylboron-Containing Materials for High-Performance OLEDs *Hudson Z.M., $Wang S.
17:40 01130 Electron-Transport Materials Built on an Intramolecular B-N Coordination Scaffold: Synthesis and Properties of Boryl-Substituted 5, 5'-Bis (2-pyridine)-2,2'-bithiophene Rao Y., Amarne H., Jia P., Wang S.
17:40 01131 Electrochemical and Spectroelectrochemical Studies of Tetraaryldiphosphine and Triarylphosphine Cation Radicals and Some Arsenic Analogues Taghavikish M., $Boeré R.
17:40 01132 Synthesis of Bifunctional Ligands: Borabenzene and Phosphole Rioux P., *Fontaine F.-G., $B-Chabot G., Maron L.
17:40 01133 Evidence for [18-Crown-6 Na]2[S2O4] in Methanol and Dissociation to Na2S2O4 and 18-Crown-6 in the Solid State; Accounting for the Scarcity of Simple Oxy Dianion Salts of Alkali Metal Crown Ethers in the Solid State Greer S., Rautiainen J.M., *Passmore J., Bruna P.J.
17:40 01134 Heavy p-Block Analogues of Thiazyl Radicals *$Rawson J., Tran T.
17:40 01135 Synthesis and Reactivity of k3-Phosphaamidines and Phosphinodiimines Mokhtabad Amrei L., $Boeré R.
17:40 01136 Characterization of (NMe4)2O3SOSO2 by Raman Spectroscopy Bruno P., Grein F., *$Passmore J., Richardson S.
17:40 01137 Reactivity of Platinum Complexes Containing a Pt-Cl-B Interaction with Borabenzene Legare M.-A., *$Fontaine F.-G.
17:40 01138 Synthesis of Unique Chalcogen - Phosphorus Compounds using Ch(II) Synthons Dube J.W., *Dutton J.L., $Ragogna P.J.
17:40 01139 Organophosphole Based Molecular Machines: Stimuli-Responsive Conformational and Photophysical Studies Ren Y., *$Baumgartner T.
17:40 01140 Spin Catalytic Transformation of Organic Molecules by Nitric Oxide Rosadiuk K., *Bohle D.S.
17:40 01141 The Search for Novel Boron-Based Lewis Acids for Use in Frustrated Lewis Pair Chemistry Neu R.C., $Stephan D.W.
17:40 End of Session


Tuesday AM

IN8510d

General Session

Organizer(s) - C. Reber
Chair(s) - S.A. Johnson

08:00 01142 Trinuclear Ni Oxazoline Complexes: Structures and Reactivities *$Gossage R.A., Foucher D.A., Lough A.J., Quail J.W., Resanovic S., Wylie R.S.
08:20 01143 Deoxygenation of C-Nitroso Metal Complexes as a Strategy to Form Nitrenoid Species *$Ottenwaelder X.
08:40 01144 An Improved Precursor for Palladium(0) Sonogashira Cross-Coupling Reactions Jaksic B., Jang J.S., *$Baird M.C.
09:00 01145 Pd(g3-1-PhC3H4)(g5-C5H5) as an Improved Precatalyst for Palladium(0) Cross-Coupling Reactions Fraser A.W., *$Baird M.C.
09:20 01146 Investigations into the Reactivity of Carbon Monoxide with Terminal Molybdenum Nitrides Cozzolino A.F., $Cummins C.C.
09:40 01147 Pushing the Boundaries in our Understanding of the Solid-State Structures of Alkali Metal Amidoborane Complexes *$Wolstenholme D.J., Che F., Titah J., Flogeras J., Decken A., McGrady G.S.
10:00 Coffee Break
10:20 01148 Original P-C Bond Activation Upon Coordination of a Diphosphine-Phosphine Oxide Ligand on Nickel(0) or Palladium(0) Derrah E.J., Ladeira S., Bouhadir G., Miqueu K., *Bourissou D.
10:40 01149 Disassembly of Diruthenium(II,III) Tetraacetate with Various P-N Donor Ligands Essoun E., *$Aquino M.A.S
11:00 01150 Multiple Ge-H Bond Activations at Adjacent Rh/Ir Centres Mobarok M.H., McDonald R., Ferguson M.J., *$Cowie M.
11:20 End of Session

IN5510b

Main Group Chemistry: Fundamentals and Applications

Organizer(s) - P. Ragogna; A. Dyker
Chair(s) - Bobby Ellis

08:00 01151 Molecular Magnesium(I) Compounds: "Bespoke" Reducing Agents for the Synthetic Chemist Jones C.
08:40 01152 Structures and Electronic Properties of Linear and Branched Oligogermanes Weinert C.S., Samanamu C.R., Schrick A.C., Roewe K.D.
09:00 01153 Merging the Chemistry of Electron-Rich Olefins (ERO) with Imidazolium Ionic Liquids Sherren C., Mu C., McKenzie I., McCollum B., Brodovitch J.-C., Percival P., Storr T., Seddon K., Walsby C., *$Clyburne J.A.C.
09:20 01154 Late Transition Metal Borane Complexes: Synthesis, Metal-Ligand Bonding, and Reactivity *$Emslie D.J.H., Kolpin K.B., Cowie B.E., Thompson J., Parker K.D., Oakley S.R.
09:40 01155 Tuning Mechanism for the Dehydrocoupling of Main-Group Substrates *Waterman R.
10:00 Coffee Break
10:20 01156 The Synthesis of (SO2)32- and O3SOSO22- as Salts of Large Cations by the Reversible Reaction of the Corresponding Dithionite and Sulfate Salts with SO2 at Room Temperature Bruna P.J., Greer S., Grein F., Leblanc F., Mailman A., *$Passmore J., Paulose T.A.P., Rautiainen M., Richardson S.
10:40 01157 Halogenated closo-dodecaborates [B12X12]2- (X = F, Cl, Br, I) *$Knapp C.
11:20 End of Session

IN1511c

Symposium in Honour of John Harrod

Organizer(s) - I.S. Butler; D. Zargarian
Chair(s) - Georgii Nikonov

08:00 01158 Pincer-Type Complexes of Divalent and Trivalent Nickel: Synthesis via C-H Nickellation, Structures, and Redox Behaviour *$Zargarian D., Spasyuk D., Benhamou L., Vabre B.
08:20 01159 Silylplatinum Complexes and the Chalk-Harrod Mechanism Puddephatt R.J., Hamilton M.J.
09:00 01160 Continuous Direct Analysis of Homogeneous Organometallic Reactions by ESI-MS *$McIndoe J.S., Vikse K.L., Ahmadi Z., Luo J., Manning C.
09:20 01161 Mechanisms of Mo Catalyzed Hydrosilylation Khalimon A.Y., Shirobokov O.G., *$Nikonov G.I.
10:00 Coffee Break
10:20 01162 Preparing Functionalized Oligosilanes via Catalytic Dehydrocoupling Skjel M.K., Lee P.T.K., *$Rosenberg L.
10:40 01163 Activation of Greenhouse Gases by Frustrated Lewis Pairs *$Stephan D.W., Neu R., Ménard G., Dömer J., Zhao X.
11:20 End of Session

IN3516b

Metallosupramolecular Assemblies - Structures, Properties and Applications

Organizer(s) - M. Murugesu; L. Thompson; G. Hanan
Chair(s) - G.S. Hanan

08:00 01164 New Ferrocene Based Dithiolate Ligands for Nanocluster Assembly Khalili B., *Corrigan J.F.
08:20 01165 Metal Organic Frameworks for CO2 Capture *$Shimizu G.K.H., Vaidhyanathan R., Iremonger S.S., Woo T.K., Boyd P., Alavi S., Martens I.
09:00 01166 Metallosupramolecular Architectures Based on "Click" Ligands Wu N., Melan C., Fleischel O., *$Petitjean A.
09:20 01167 Iridium Hemicage Chelates: Lessons Learned in Luminophore Design *$Zysman-Colman E.
09:40 01168 Prussian Blue Nanomaterials *$MacLachlan M.J., Roy X.
10:00 Coffee Break
10:20 01169 Polynuclear Metal Complexes and Extended Networks: Exploring the Landscape of Possibilities for Magnetic and Electrical Bistabilty Dunbar K.R.
11:00 01170 Rational Design of Magnetic Materials Based on "Single-Molecule Magnet" Building-Blocks *$Clérac R.
11:20 End of Session


Tuesday PM

IN5510b

Main Group Chemistry: Fundamentals and Applications

Organizer(s) - P. Ragogna; A. Dyker
Chair(s) - C. Adam Dyker

Strem Chemicals Award for Pure or Applied Inorganic Chemistry Lecture

13:40 01171 Adventures in Phosphorus Chemistry: A Journey from Molecules to Polymers and Back Again Gates D.P.
14:20 01172 Substitution Matters: Understanding the Reactivity of Main Group Halides with a-Diimine Ligands Martin C.D., *$Ragogna P.J.
14:40 01173 Structures and Properties of Semi-quinone Bridged Bisdithiazolyls Yu X., Mailman A.M., *$Oakley R.T.
15:00 01174 Synthesis and Coordination Chemistry of Phosphide- and Boryl-Based PPP- and PBP-Pincer Complexes Borau-Garcia J., Bosch M.J., Tuononen H.M., *$Roesler R.
15:20 01175 Spirocyclic Group 13 Complexes of Bis(pyridyl)methyl and Bis(isopropylamino)naphthalene $Moilanen J., Borau-Garcìa J., Hänninen M. M., Peuronen A., Roesler R., *Tuononen H.M.
15:40 Coffee Break
16:00 01176 Bis(imino)pyridine Complexes of Tl(I): Exploring Weak Covalent Interactions and Dimer Formation Jurca T., Korobkov I., Gorelsky S.I., Richeson D.S.
16:20 01177 Activation of Simple Olefins and Dienes with Low-Valent Gallium Caputo C.A., Zhu Z., Fettinger J.C., *$Power P.P.
16:40 01178 Understanding the Reactivity of Strained Sandwich Compounds with Aluminum or Gallium in Bridging Positions: Experiments and DFT Calculations Bagh B., Green J.C., *$Müller J.
17:00 01179 Novel Phosphorus Oxide Cages from a Diphosphorus Trication and Formamides Echterhoff A.K.C., *$Weigand J.J.
17:20 01180 Donor-Acceptor Complexes of Main Group Elements with Unusual Bonds Frenking G.
18:00 End of Session

IN3516b

Metallosupramolecular Assemblies - Structures, Properties and Applications

Organizer(s) - M. Murugesu; L. Thompson; G. Hanan
Chair(s) - M. Murugesu

13:40 Strem Award Lecture at 13:40 in IN5 room 510b.

14:20 01181 Structural and Reactivity Studies on Oxidized Bimetallic Schiff-base Systems *$Storr T., Dunn T.J., Simmonds C.J.
14:40 01182 Metal-containing Oligothiophenes: Complexes, Coordination Polymers and Properties *$Wolf M.O., Earl L., Kuchison A.M., Moore S.A.
15:00 01183 Photoinduced Charge Storage in Supramolecular Photocatalysts with Multiviologen Tethers and Applications to Hydrogen Evolution from Water Sakai K.
15:40 Coffee Break
16:00 01184 Applications of Coordination Chemistry in the Synthesis of Single-Molecule Magnets Rinehart J.D., Meihaus K.R., Zadrozny J.M., Harris T.D., Freedman D.E., Bechlars B., D'Alessandro D.M., Dechambenoit P., Jenkins D.M., *Long J.R.
16:40 01185 Engineering Magnetic Molecular Compounds: Design of Single Chains Magnets and Magnetic Metal Organic Framework *$Journaux Y., Pardo E., Ferrando-Soria J., Lescouëzec R., Lisnard L., Chamoreau L.M., Li Y., Pereira C., Novak M., Ruiz-García R., Lloret F., Julve M., Cano J., Ruiz-Pérez C.
17:00 01186 Bimetallic Coordination Chemistry Based on Indigo *$Hicks R.G., Nawn G., Oakley S.R., Waldie K.M.
17:20 01187 Diverse Efforts Toward High Spin Polymetallic Complexes and Magnetic Metallopolymers *$Lemaire M.T., Revunova K., Dowling M., Kwong W.-T., Bell R.
17:40 01188 Rotaxanes as Ligands in Metal-Ligand Self-Assembly Viljoen E., *$Loeb S.J.
18:00 End of Session

IN2511c

Metal-catalysed Polymerisation (joint with MS8)

Organizer(s) - F. Schaper
Chair(s) - Parisa Mehrkhodavandi; Stephen Foley

13:40 Strem Award Lecture at 13:40 in IN5 room 510b.

14:20 01189 Amine-phenolate Zinc Complexes in Ring-Opening Polymerizationof Lactide and e-Caprolactone Ikpo N., *Kerton F.M.
14:40 01190 Three-coordinate Diamido Aluminum Complexes for Applications in Cyclic Ester Polymerizations *$Foley S.R., Chitanda J.M., Oberhofer A., Olson J.A., Prokopchuk D.E.
15:00 01191 Catalysts Based on Oxophilic Metals for Stereoselective and Highly Productive ROP of Cyclic Esters *Carpentier J.F.
15:40 Coffee Break
16:00 01192 Synthesis of M (II) b-Diketiminate Complexes as Catalysts for Ring Opening Polymerization of Lactide Whitehorne T.J.J., *Schaper F.
16:20 01193 Mechanistic Insights into Living Polymerization of Cyclic Esters by Chiral Indium Catalysts $Mehrkhodavandi P., Yu I., Acosta Ramirez A., Xu C., Osten K.
16:40 01194 Pursuit of Enhanced Activity and Stereoselectivity Through Ligand Design: Ring-opening Polymerization of Lactide Using Well-defined Cationic Zinc Catalysts *$Hayes P.G., Wheaton C.A., Sun H.
17:00 01195 Catalytic Ring-Opening Polymerisation of Renewable Macrolactones to High Molecular Weight Polyethylene-like Polymers *Duchateau R., $van der meulen I., Gubbels E., Heise A., Koning C.E.
17:20 01196 Vanadium Mediated Radical Polymerization *Shaver M.P., Allan L.E. N., Jones M.R., Hanhan M.E.
17:40 01197 Effects of Electronic Ligand Variation on Cobalt-Mediated Radical Polymerization of Vinyl Acetate Sherwood R.K., Black J.O., *$McNeil W.S.
18:00 End of Session


Wednesday AM

IN8511d

General Session

Organizer(s) - C. Reber
Chair(s) - M. MacLachlan

08:00 01198 Vinyl Boranes and Their Use in Catalytic Metal-Free Imine Hydrogenation Mahdi T., *$Stephan D.W.
08:20 01199 Group 15 and 16 Cations Coordinated to a Bithiophene or Bithiazole Backbone Price J.T., *Lui M., $Ragogna P.J.
08:40 01200 Ylide-based Super Electron Donors Hanson S.S., *Dyker C.A.
09:00 01201 Donor-Acceptor Stabilization: A New Approach Towards the Isolation of Heavy Methylene Analogues Al-Rafia S.M.I., Liew S.K., Ferguson M.J., *$Rivard E.
09:20 01202 Interpnictogen Compounds Chitnis S.S., *$Burford N.
09:40 01203 Activation and Transformation of Small Molecules Using Al-Halide Based Frustrated Lewis Pairs Ménard G., Stephan D.W.
10:00 Coffee Break
10:20 01204 Synthesis, Characterization and Properties of Functional Poly(alkyl-phenylene oxide)s Bearing Vinyl, Epoxy, Aldehydic and Acrylate Groups *$Liang M.
10:40 01205 From Umbrellas to Polymeric Solar Cells *$Rivard E., Kang L., Lummis P.A., Malcolm A.C., Al-Rafia S.M.I., Liew S.K., Goettel J., Barnes M., Ramsay W.
11:00 01206 In Situ Polymerization of N-silylsulfonimidoyl Chlorides: A Lewis Acid Catalyzed Route to Poly(oxothiazene)s *$McWilliams A.R., Aldeva V., Gezahegn S., Panahi B., Quinn J., Shuoprasad M., Lough A.J.
11:20 01207 Side Chain Co(I) Polymers Featuring Neutral 18 Electron CpCoCb Units *$Ragogna P.J., Chadha P.
11:40 01208 Enantiomerically Pure Phosphaalkene-Oxazolines (PhAk-Ox): Applications in Polymer Synthesis and Asymmetric Catalysis Dugal-Tessier J., Dake G.R., *Gates D.P.
12:00 01209 Phosphole-based p-Conjugated Materials *$Baumgartner T.
12:20 End of Session

IN3516b

Metallosupramolecular Assemblies - Structures, Properties and Applications

Organizer(s) - M. Murugesu; L. Thompson; G. Hanan
Chair(s) - L.K. Thompson

08:00 01210 Kubas-Type Hydrogen Storage in Metallo-Polymer Materials Hoang T., Trudeau M., *$Antonelli D.
08:20 01211 Metallosupramolecular Polymers *Kurth D.G.
09:00 01212 Influence of Noncovalent Interactions on the Properties of EuII *$Allen M.J., Garcia J., Gamage N.-D. H., Haacke E.M.
09:20 01213 The Frontier of Molecular Magnetic Materials: Dithiadiazolyl and Diselenadiazolyl Coordination Complexes MacDonald D.J., $Preuss K.E., Jennings M., Lough A., Clerac R.
09:40 01214 Toward Structural Control of Magnetic Anisotropy in Metal Alkynyl Complexes *$Shores M.P., Hoffert W.A., Newell B.S., Rappe A.K.
10:00 Coffee Break
10:20 01215 Coordination Chemistry with Oximes - A Five Year Mistake Brechin E.K.
11:00 01216 Cooridination Polymers of Ag(I) and Au(I) Using Oligothiophene and Oligothiazole-Based Ligands *$MacKinnon C.D., Allard S.R., D'Aleo D.N., Andreychuk N.R., Assoud A.
11:20 01217 Isoindoline and Hydrazone Ligands Leading to Antiferromagnetic Di-, Tri- and Tetranuclear Complexes Addison A.W., Sasimovich I., Beard E.M., Lam A., Zeller M., Thompson L.K., Schmiesing C.S., Lofland S., Hunter A.D., Sinn E., Dragancea D.
11:40 01218 Control of Charge-Transfer in Covalently-Bonded Donor/Acceptor Assemblies *$Miyasaka H.
12:00 01219 Symmetric and Asymmetric Cylindrical Block Co-Micelles from Self-Assembled Polyferrocenylsilane Block Copolymers Chabanne L., Rupar P.A., Gilroy J.B., Winnik M.A., *Manners I.
12:20 End of Session

IN2511c

Metal-catalysed Polymerisation (joint with MS8)

Organizer(s) - F. Schaper
Chair(s) - Scott Collins; Frank Schaper

08:00 01220 Development of a Multicomponent Polymerization Reaction: Palladium-Catalyzed Synthesis of Conjugated Polymers from Simple Building Blocks Leitch D.C., *$Arndtsen B.A.
08:20 01221 Ti(IV) and Zr(IV) Non-chelated Methyl-alkene-metallocene Complexes: Vinylsilane Complexes as Models for NMR Characterization of Elusive Polymerization Intermediates Dunlop-Bière A.F., *Baird M.C.
08:40 01222 Chain Walking and Long Chain Branching in Metallocene Polymerization *$Budzelaar P.H.M.
09:00 01223 Pd Catalyzed Copolymerization of Ethylene with Functional Polar Monomers Claverie J.P., Piche L., Daigle J.C.
09:20 01224 Metal Catalyzed Copolymerization of Olefins with Polar Vinyl Monomers *$Jordan R.F.
10:00 Coffee Break
10:20 01225 Coordination Chemistry of New Bidentate and Tridentate Imino-N-heterocyclic Carbene Ligands and Polymerization Activity of the Corresponding Complexes *$Lavoie G.G., Badaj A.C., Larocque T.G., Al Thagfi J., Dastgir S.
10:40 01226 Selective Ethylene Oligomerization *$Gambarotta S., Duchateau R.
11:00 01227 Branched Polyphenylacetylene Collins S., *$Jimenez M.V., Angoy M., Vispe E., Bartolome M.I., Perez-Torrente J.P., Podzimek S., Lebeda P.
11:20 01228 Insight into the Chromium Promoted Ethylene Oligomerization: Role of the Metal Oxidation State, Ligand and Activators *Shaikh Y., $Albahily K., Gambarotta S.
11:40 01229 A Ruthenium Catalyst Yielding Crosslinked Polyethylene Piche L., *Claverie J.P.
12:00 01230 Imidazol-2-imine Family of Ligands and Application in Olefin Polymerization Dastgir S., *$Lavoie G.G.
12:20 End of Session

IN9511e

Advances in Solar Energy Conversion: Solar Cells and Beyond (joint with EG3)

Organizer(s) - J.F. Morin; E. Zysman-Colman; M. Leclerc
Chair(s) - Mario Leclerc; Curtis Berlinguette

08:00 See EG3.

12:20 End of Session

IN4513d

Organometallic Reagents for Organic Synthesis (joint with OR3)

Organizer(s) - S. Collins; B. Arndtsen
Chair(s) - Arndtsen

08:00 See OR3.

12:20 End of Session

IN6516a

Radiopharmaceuticals and Imaging (joint with BM3)

Organizer(s) - R. Schirrmacher; P. Caravan
Chair(s) - Peter Caravan; Martin Lepage

08:00 See BM3.

12:20 End of Session


Wednesday PM

IN8511d

General Session

Organizer(s) - C. Reber
Chair(s) - D.Foucher; E. Rivard

13:40 01231 Synthetic Studies in Molecular, Macromolecular, and Supramolecular Chemistry Manners I.
14:00 01232 The Influence of Inorganic Nanocrystals on the Shape of Block Copolymer Micelles in Solution *$Winnik M.A., Zhang M., Hu Y., Hassan Y., Scholes G.D., Rene-Boisneuf L.
14:20 01233 Preparation and Properties of the Metallacycloalkanes Composed of Heavier Group 14 Elements Tanabe M., *Osakada K.
14:40 01234 Regioselective Hydrostannation of Alkynyltin Compounds: Synthesis of 1,1-Bis(tributylstannyl)alkenes and Novel Cyclic Organotin Species *$Sheridan J.B., Liu C.
15:00 01235 Pentafluorophenylcopper: From Luminescent Complexes to Versatile Reagents *$Jaekle F.
15:20 01236 Synthesis, Characterization and Properties of Metal Coordination Prussian Blue Nanoshells via Miniemulsion Periphery Polymerization *$Wang X.-S.
15:40 Coffee Break
16:00 01237 Platinum-Containing Macrocycles that Stack *$MacLachlan M.J., Frischmann P.D., Guieu S.
16:20 01238 Beyond Carbon and Hydrogen: New Materials for Ion-Exchange Membranes Peckham T.J., Thomas O.D., Soo K., Kulkarni M., Thanganathan U., Yang Y., *$Holdcroft S.
16:40 01239 Canadian Inorganic Chemistry: Making Fiscal and Environmental Green Impact Resendes R.
17:00 01240 Progress in the Preparation of Stable Polystannanes and other Tin Containing Polymers $Foucher D.A., Khan A., Ward J., *Al-Faouri T.
17:20 01241 "Soft" Living Polymerizations: Metal-Containing Homopolymers and Block Copolymers from Photocontrolled Ring-Opening Polymerizations Chabanne L., Matas Ruiz I., Patra S.K., *Manners I.
17:40 01242 Generation of Ruthenium Hydrides from Propagating and Quenched Olefin Metathesis Catalysts Beach N.J., *Fogg D.E.
18:00 End of Session

IN3516b

Metallosupramolecular Assemblies - Structures, Properties and Applications

Organizer(s) - M. Murugesu; L. Thompson; G. Hanan
Chair(s) - A. Petitjean; G.K.H. Shimizu

13:40 01243 Self-assembled Molecular Spheres *$Fujita M.
14:20 01244 Ligand Design for Multifunctional Molecule-Based Magnetic Materials *$Pilkington M.
14:40 01245 Identifying Orbital Mixing Trends in Lanthanide/Actinide Extractants *$Kozimor S.A., Boland K.S., Batista E.R., Daly S.R., Clark D.L., Gaunt A.J., Keith J.M., Klaehn J.R., Martin R.L., May I., Minasian S.G., Peterman D.R., Scott B.L., Wagner G.L.
15:00 01246 Dirhodium (II, II) Tetramidinate Complexes and their Coupling Products: Structural and Electrochemical Properties Pal A.K., Brochery V., Hanan G.S.
15:20 01247 Hetrotrimetallic Complxes: Synyhetic Approaches and Magnetic Properties Andruh M.
15:40 Coffee Break
16:00 01248 Properties of Coordination Polymer Materials based on Cyanoaurate(III)-based Building Blocks *Leznoff D.B.
16:40 01249 Ferromagnetic Copper Chloride Chains: Effects of Randomness Herringer S.N., *Turnbull M.M., Landee C.P., Ribas-Arino J., Deumal M., Novoa J.J.
17:00 01250 Polynuclear Iron Complexes (Fen; n = 1-9) with Ditopic and Tritopic Ligands ­ Diverse Structures, Magnetism and Spin State Analysis Thompson L.K., Anwar M.U., Dawe L.N.
17:20 01251 Bi(1,3,5-triazine); A Novel Scaffold for the Preparation of Multinuclear Transition Metal Complexes Reid D.J., Cull J.E.W., Thompson R., Chisholm K.D.S., *$Scott J.
17:40 01252 The Search for New Ligands to Produce Self-assembled Polymetallic Clusters Anwar M., *$Thompson L., Dawe L.N.
18:00 End of Session

IN9511e

Advances in Solar Energy Conversion: Solar Cells and Beyond (joint with EG3)

Organizer(s) - J.F. Morin; E. Zysman-Colman; M. Leclerc
Chair(s) - Eli Zysman-Colman; Gerard van Koten

13:40 See EG3

18:00 End of Session

IN4516c

Organometallic Reagents for Organic Synthesis (joint with OR3)

Organizer(s) - S. Collins; B. Arndtsen
Chair(s) - Collins

13:40 See OR3.

18:00 End of Session

IN6516a

Radiopharmaceuticals and Imaging (joint with BM3)

Organizer(s) - R. Schirrmacher; P. Caravan
Chair(s) - Bjoern Waengler; Ralf Schirrmacher

13:40 See BM3.

18:00 End of Session

IN7511c

Metals in Enzymes (joint with BM14)

Organizer(s) - D.S. Bohle
Chair(s) - D. Scott Bohle

13:40 01253 Theoretical Spectroscopy of Open-Shell Transition Metal Complexes with Strong Spin Orbit Coupling *Neese F.
14:20 01254 Magnetic Properties of Two Trinuclear Copper Compounds: A Density Functional Theory Study Zhekova H.R., Seth M., *Ziegler T.
14:40 01255 Formation and Reactivity of a Biomimetic Hydroperoxocopper(II) Cryptate Chaloner L., Askari M.S., Kutteh A., *$Ottenwaelder X.
15:00 01256 Advanced Paramagnetic Resonance Studies of Nitrogenase Intermediates: Unravelling the Fe Ions of the Iron Molybdenum Cofactor Telser J., *Doan P.E., Lukoyanov D., Barney B.M., Dean D.R., Seefeldt L.C., $Hoffman B.M.
15:20 01257 Modelling the 2-His-1-Carboxylate Facial Triad: Development of the Bis(Imidazolyl)proprionate (BIP) Ligand Family Moelands M.A.H., Goossen M., *Klein Gebbink R.J.M.
15:40 Coffee Break
16:00 01258 Electronic Structure Contributions to the Activity of NO Releasing Agents Okbinoglu T., *$Kennepohl P.
16:20 01259 Binding of Divalent Metal Ions to Calcium Free Peroxidase: A Thermodynamic and Kinetic Study *$Nazari K., Kelay V., Mahmoudi A., Hashemianzadeh M., Amin A.H.
16:40 01260 The Two Spin States of a Copper(II)-Superoxide Mimic Askari M.S., Girard B., *$Ottenwaelder X.
17:00 01261 Silica-Nanoprobes as New Tools for Bacterial Biofilm Exploration Mauline L, Gressier M, Roques C, Menu MJ
17:20 End of Session

UPC-I517ab

Undergraduate Student Poster Competition

17:40 01262 Non-leachable Flame Retardant Additives for Paper Tian H., *Hu T., $Gates D.P.
17:40 01263 Silver-Olefin and Alkyne Complexes Supported by the Bis(imino) Pyridine Scaffold Ouanounou S., Richeson D.S., Jurca T.
17:40 01264 Synthesis and Characterization of Cobalt Amine-(bis)phenolate Complexes Saunders L.N., Kozak C.M., Kerton F.M.
17:40 01265 Aluminum Complexes as Efficient Catalysts for the Preparation of Cyclic Carbonates Drover M., Ikpo N., *Kerton F.M.
17:40 01266 Chiral Induction via the Disassembly of Diruthenium(II,III) Tetrabenzoate Groves B.R., *$Aquino M.A.S.
17:40 01267 N,N'-Disubstituted 1,8-Diaminonaphthalene Ligands Employed in the Comparison of the Synthesis of the TaMe3(1,8-(3-5-Me2C6H3N)2C10H6) Complex Theriault A., Richeson D.S.
17:40 01268 Cobalt(II)/(III) Complexes of Amine-bis(phenolate) Ligands as Catalysts for Reactions of Carbon Dioxide and Propylene Oxide Pratt M.E., Saunders L., Dean R., *Kozak C.M.
17:40 01269 Synthetic and Structural Studies 1-Alkyl-2,1,3-Benzoselenadiazolium Iodides Lee L.M., Vargas-Baca I.
17:40 01270 Photophysics of Ru(II) Dyads Based on (Pyren-1-yl)ethynyl Derivatives of 1,10 Phenanthroline Lincoln R.A., $McFarland S.A.
17:40 01271 Catalytic Transformations of Biomass Price C.N., $Kerton F.M.
17:40 01272 Synthesis, Characterization, and Biological Assays of Hetero-Multinuclear Metal Complexes Taylor I., Philpott J., Hu Y., Tibbetts M., *Anderson C.
17:40 01273 Reductive Elimination from Cyclometalated Platinum Complexes with Chelate Ligands to Form Eventually New Cyclometalated Species that Contain an sp3-sp2 coupling or Bis-Cyclometalated Species Kfoury N., Morris J., Scheetz P., Weinstein M., Crespo M., *Anderson C.
17:40 01274 Metalation Resistant Ligands for Supporting Organometallic f-Element Complexes Kamenz B.L., Johnson K.R.D., $Hayes P.G.
17:40 01275 The First Structurally Characterized Exo Isomers of 3-Phosphinimino-1,3,5-trithia-2,4,6,8-tetrazocines Suduweli Kondage S., *$Boeré R.T., Roemmele T.L.
17:40 01276 Synthesis and Characterization of Cyclic Tetraelphosphonium Cations Lucas S.H., Macdonald E., Burford N.
17:40 01277 Helicate to Mesocate Switch Through Ligand Modifications Habib F., Long J., Lin P-H., Redouane C., Korobkov I., Wernsdorfer W., *$Murugesu M.
17:40 01278 Ruthenium Complexes of Imidazo[4,5-f][1,10]phenanthroline and Oxazo[4,5-f][1,10]phenanthroline for Bioinorganic Applications DeCoste R.
17:40 End of Session


Thursday AM

IN8511d

General Session

Organizer(s) - C. Reber
Chair(s) - X. Ottenwaelder

The Award for Graduate Work in Inorganic Chemistry lecture will be in IN4 at 11:00

08:00 01279 Competitive Geminal C-H and C-F Activation of Fluoroolefins by Adjacent Metal Centers *Slaney M.E., $Cowie M.
08:20 01280 C-H and C-F Bond Activation by Ni(0) Complexes: Does Phosphine Size Matter? Hatnean J.A., *Johnson S.A.
08:40 01281 Chemoselective Diamine Synthesis via the Buchwald-Hartwig Amination of Aryl Chlorides Employing DalPhos Ancillary Ligands Tardiff B.J., *Stradiotto M.
09:00 01282 Oxidation of Polystyrene using C-H Activating Non-Heme Iron Catalysts McArthur S., *$Baird M.C.
09:20 01283 Differing Reactivities of Cp*M(NO)(alkyl)(g3-allyl) Complexes of Molybdenum and Tungsten Chow C., Baillie R.A., Man R. W. Y., $Legzdins P.
09:40 01284 Di-NHCs, Di-MICs, and Hybrid NHC/MICs as Bridges in Mixed-Metal Systems Zamora M.T., Ferguson M.J., McDonald R., *$Cowie M.
10:00 Coffee Break
10:20 01285 Chiral Phosphonium Indenylide Complexes of Ruthenium Fowler K.G., Littlefield S.L., $Baird M.C.
10:40 01286 Unique Coordination of Aryl Isonitriles with Rhodium-Iron Complexes of an Ambiphilic Ligand Cowie B.E., *Emslie D.J.H.
11:00 01287 Transfer of Chirality to Metal Centers: A Novel Approach Groves B.R., Lundrigan T.L., Vadavi R., *$Aquino M.A.S.
11:20 01288 Tantalum(V) Boronate Metallocavitands: Towards Hosting C60 Garon C.N., *Fontaine F.-G.
11:40 01289 Gold(II) Phthalocyanine Revisited Wong E.W.Y., Miura A., Wright M.D., Walsby C.J., Shimizu S., Kobayashi N., *$Leznoff D.B.
12:00 01290 Luminescence in Square-Planar Ni(II) Complexes : Unusual Properties of a Pincer Family Baslon V., Reber C.
12:20 End of Session

IN3516b

Metallosupramolecular Assemblies - Structures, Properties and Applications

Organizer(s) - M. Murugesu; L. Thompson; G. Hanan
Chair(s) - J. Scott; M. Pilkington

The Award for Graduate Work in Inorganic Chemistry lecture will be in IN4 at 11:00

08:00 01291 Preparation and Characterization of Mixed ligand Chitosan Complexes of Zn(II) and Ag(I) Mostafa S.I., Mostafa Sahar, Butler I.S.
08:20 01292 Incorporating Mechanically Interlocked Components into Metallosupramolecular Assemblies Zhu K., Vukotic V.N., Mercer D.J., *$Loeb S.J.
09:00 01293 Optimization of a Family of Single-Molecule Magnets *$Glaser T.
09:20 01294 Ferrocenyl Functionalized Silver-Chalcogenide Nanoclusters *$Corrigan J.F., MacDonald D.G., Eichhöfer A., Kübel C., Campana C.F.
09:40 01295 Photomagnetic Mixed-valence Compounds : From Networks to Molecules $Mathonière C., Holmes S.M., Clérac R., Zhang Z., *Li D.
10:00 Coffee Break
10:20 01296 Multitasking Molecular Magnets Powell A.K.
11:00 01297 Pressure-induced Jahn-Teller Switching in a Mn12 Nanomagnet Parois P., Moggach S.A., Sanchez-Benitez J., Kamenev K.V., Lennie A.R., Warren J.E., Brechin E.K., Parsons S., *$Murrie M.
11:20 01298 Polynuclear Complexes: On the Track of Molecular Size Magnets *Luneau D.
11:40 01299 Photoinduced Magnetization Effects in Nanometer Scale Heterostructures of Prussian Blue Analogs Talham D.R.
12:00 01300 Transition Metal Complexes of Some Ditopic and Tetratopic Ligands Towards Large [nxn] Square Grids (n = 2 - 4) Elliott A.S., Thompson L.K., Dawe L.N.
12:20 End of Session

IN9511e

Advances in Solar Energy Conversion: Solar Cells and Beyond (joint with EG3)

Organizer(s) - J.F. Morin; E. Zysman-Colman; M. Leclerc
Chair(s) - Mario Leclerc; Jean-Francois Morin

08:00 See EG3.

12:20 End of Session

IN4516c

Organometallic Reagents for Organic Synthesis (joint with OR3)

Organizer(s) - S. Collins; B. Arndtsen
Chair(s) - Collins

08:00 See OR3.

12:20 End of Session

IN6516a

Radiopharmaceuticals and Imaging (joint with BM3)

Organizer(s) - R. Schirrmacher; P. Caravan
Chair(s) - Raman Chirakal; Ralf Schirrmacher; Peter Caravan

08:00 See BM3.

12:20 End of Session

IN7511c

Metals in Enzymes (joint with BM14)

Organizer(s) - D.S. Bohle
Chair(s) - D. Scott Bohle

The Award for Graduate Work in Inorganic Chemistry lecture will be in IN4 at 11:00.

08:00 01301 Synthesis, Structural Characterization and Antitumor Activity of Some New Transition Metal Complexes of 6-amino-4-hydroxy-2-thiopyrimidine Elsayed S.A., El-Hendawy A.M., Mostafa S.I., Jean-Claude B.J., *$Butler I.S.
08:20 01302 Mechanistic Studies of the Heme Iron-containing Dehaloperoxidase from A. ornata Using Proximal and Distal Active Site Mutants *$Dawson J.H., Du J., Huang X., Lebioda L., Sono M.
09:00 01303 Taming P450 Enzymes for Biocatalysis and Nanobiotechnologies *$Auclair K.
09:20 01304 Biosynthesis of the E. coli Iron Chelator Enterobactin: Expanding The Assembly Line *$Pawelek P.D.
09:40 01305 Targeting Serum-protein Interactions in the Design of New Ruthenium(III) Anti-cancer Complexes *$Walsby C.J., Mu C., Webb M.I.
10:00 Coffee Break
10:20 01306 Theoretical Study on the Mechanism of the Oxygen Activation Process in Cysteine Dioxygenase Enzymes *$de Visser S.P.
11:00 01307 Leaves are Green, so Why isn't Blood Green? *Stillman M.
11:20 01308 Ferrocenyl Carbohydrate Chloroquine Conjugates as Potential Antimalarial Agents Herrmann C., Salas P.F., Adam M.J., *$Orvig C.
11:40 01309 The Mitochondrial Heme Cytochrome c Peroxidase is a Key Modulator of Aging in Yeast Cells Martins D., Kathiresan M., *$English A.M.
12:00 End of Session


Thursday PM

IN3516b

Metallosupramolecular Assemblies - Structures, Properties and Applications

Organizer(s) - M. Murugesu; L. Thompson; G. Hanan
Chair(s) - D.B. Leznoff; S.J. Loeb

15:00 01310 Metal Complexes with Multi-bistability *Oshio H.
15:40 Coffee Break
16:00 01311 Supramolecular Arrangements of Lanthanide Single-Molecule Magnets Murugesu M.
16:40 01312 Photoactive Neutral Re(I) Complexes for Supramolecular Anion Sensing: A Binding Study Bessette A., Pal A.K., Nag S., *Hanan G.S.
17:00 01313 Novel Metal Organic Frameworks using Structure Directing, Shape-Persistent Ligands Crane A.K., Wong E.Y.L., $MacLachlan M.J.
17:20 01314 Triarylboron-Containing Self-Assembled Materials Blight B.A., *Wang S.
17:40 01315 Organic Molecules Linked by Metal Atoms: Sandwich- and Trap-type Interfaces *$Naumkin F.Y., Kochhar G.
18:00 End of Session

IN9511e

Advances in Solar Energy Conversion: Solar Cells and Beyond (joint with EG3)

Organizer(s) - J.F. Morin; E. Zysman-Colman; M. Leclerc
Chair(s) - Jean-Francois Morin; Tim Bender

15:00 See EG3.

18:00 End of Session

IN4516c

Organometallic Reagents for Organic Synthesis (joint with OR3)

Organizer(s) - S. Collins; B. Arndtsen
Chair(s) - Arndtsen

14:40 See OR3.

18:00 End of Session

IN6516a

Radiopharmaceuticals and Imaging (joint with BM3)

Organizer(s) - R. Schirrmacher; P. Caravan
Chair(s) - Neil Vasdev

14:40 See BM3.

18:00 End of Session


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